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Acta Cryst. (2005). E61, m522-m524  [ doi:10.1107/S1600536805004216 ]

Bis(adamantylamine-[kappa]N)bis(1-phenylbutane-1,3-dionato-[kappa]2O,O')nickel(II)

E. Mestrovic and D.-K. Bucar

Abstract: In the title complex, [Ni(C10H9O2)2(C10H17N)2], the Ni atom, which occupies a special position at an inversion centre, has an octahedral environment formed by four O atoms of two chelate benzoylacetonates [Ni-O 2.0409 (16) and 2.0187 (16) Å, and O-Ni-O 90.36 (6)°] and two N atoms of the adamantylamine ligands [Ni-N = 2.176 (2) Å]. The amine H atoms of the adamantylamine ligands do not participate in any hydrogen bonds, due to their steric shielding and the lack of accessible acceptors.

Online 12 February 2005


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