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In the crystal structure of the title compound, poly­[[cobalt(II)-di-μ3-formato] di­methyl­form­amide 0.33-solvate] [Co(CHO2)2]·0.33C3H7NO, the units of Co(HCO2)2 are assembled into a three-dimensional framework through carboxyl­ate bridging. The four symmetry-independent Co atoms show nearly regular octahedral coordination; two of them lie on inversion centres.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805007786/bt6622sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536805007786/bt6622Isup2.hkl
Contains datablock I

CCDC reference: 250019

Key indicators

  • Single-crystal X-ray study
  • T = 295 K
  • Mean [sigma](O-C) = 0.004 Å
  • Disorder in solvent or counterion
  • R factor = 0.033
  • wR factor = 0.079
  • Data-to-parameter ratio = 13.5

checkCIF/PLATON results

No syntax errors found



Alert level C ABSTM02_ALERT_3_C The ratio of expected to reported Tmax/Tmin(RR') is < 0.90 Tmin and Tmax reported: 0.537 0.767 Tmin' and Tmax expected: 0.692 0.764 RR' = 0.773 Please check that your absorption correction is appropriate. PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings Differ .... ? PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............ 0.33 Ratio PLAT061_ALERT_3_C Tmax/Tmin Range Test RR' too Large ............. 0.76 PLAT243_ALERT_4_C High 'Solvent' Ueq as Compared to Neighbors for O13 PLAT243_ALERT_4_C High 'Solvent' Ueq as Compared to Neighbors for C7' PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for N1 PLAT250_ALERT_2_C Large U3/U1 Ratio for Average U(i,j) Tensor .... 2.41 PLAT302_ALERT_4_C Anion/Solvent Disorder ......................... 38.00 Perc. PLAT432_ALERT_2_C Short Inter X...Y Contact O13 .. C3 .. 2.98 Ang. PLAT432_ALERT_2_C Short Inter X...Y Contact C4 .. C7' .. 3.14 Ang.
Alert level G CELLZ01_ALERT_1_G Difference between formula and atom_site contents detected. CELLZ01_ALERT_1_G ALERT: check formula stoichiometry or atom site occupancies. From the CIF: _cell_formula_units_Z 12 From the CIF: _chemical_formula_sum C3 H4.33 Co N0.33 O4.33 TEST: Compare cell contents of formula and atom_site data atom Z*formula cif sites diff C 36.00 36.00 0.00 H 51.96 52.00 -0.04 Co 12.00 12.00 0.00 N 3.96 4.00 -0.04 O 51.96 52.00 -0.04
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 12 ALERT level C = Check and explain 2 ALERT level G = General alerts; check 5 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 3 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 4 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

poly[[cobalt(II)-di-µ3-formato] dimethylformamide 0.33-solvate top
Crystal data top
[Co(CHO2)2]·0.33C3H7NOF(000) = 1036
Mr = 173.33Dx = 2.052 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 3103 reflections
a = 11.3457 (7) Åθ = 2.2–27.0°
b = 10.0117 (7) ŵ = 2.99 mm1
c = 14.820 (1) ÅT = 295 K
β = 91.372 (1)°Block, red
V = 1682.9 (2) Å30.12 × 0.10 × 0.09 mm
Z = 12
Data collection top
Bruker APEX area-detector
diffractometer
3639 independent reflections
Radiation source: fine-focus sealed tube3055 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.033
φ and ω scansθmax = 27.0°, θmin = 2.2°
Absorption correction: multi-scan
(SADABS; Bruker, 2002)
h = 1410
Tmin = 0.537, Tmax = 0.767k = 1212
9679 measured reflectionsl = 1518
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.033Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.079H-atom parameters constrained
S = 0.97 w = 1/[σ2(Fo2) + (0.0444P)2]
where P = (Fo2 + 2Fc2)/3
3639 reflections(Δ/σ)max = 0.001
270 parametersΔρmax = 0.50 e Å3
19 restraintsΔρmin = 0.36 e Å3
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Co10.50000.50000.50000.0206 (1)
Co20.00000.50000.50000.0207 (1)
Co30.24509 (3)0.42763 (4)0.36592 (2)0.01674 (11)
Co40.23945 (3)0.12263 (3)0.30462 (2)0.01856 (11)
O10.3143 (2)0.5265 (2)0.4771 (1)0.0222 (4)
O20.1518 (2)0.5967 (2)0.5439 (2)0.0327 (5)
O30.5413 (2)0.5099 (2)0.3638 (1)0.0328 (5)
O40.3716 (2)0.5167 (2)0.2854 (1)0.0221 (4)
O50.4813 (2)0.2949 (2)0.4933 (1)0.0313 (5)
O60.3432 (2)0.2510 (2)0.3868 (1)0.0221 (4)
O70.0066 (2)0.6277 (2)0.3892 (1)0.0335 (5)
O80.1524 (2)0.5900 (2)0.3076 (1)0.0218 (4)
O90.0984 (2)0.3525 (2)0.4312 (1)0.0219 (4)
O100.1036 (2)0.1362 (2)0.3934 (1)0.0265 (5)
O110.1949 (2)0.3116 (2)0.2512 (1)0.0213 (4)
O120.1936 (2)0.4540 (2)0.1347 (1)0.0292 (5)
O130.3714 (5)0.8617 (5)0.6659 (3)0.137 (2)
N10.2888 (3)1.0663 (4)0.6607 (2)0.070 (1)
C10.2586 (3)0.5950 (3)0.5345 (2)0.0249 (6)
C20.4821 (3)0.5279 (3)0.2946 (2)0.0285 (7)
C30.4237 (3)0.2191 (3)0.4439 (2)0.0273 (7)
C40.0583 (3)0.6512 (3)0.3258 (2)0.0282 (7)
C50.0624 (3)0.2335 (3)0.4330 (2)0.0258 (6)
C60.1788 (3)0.3426 (3)0.1686 (2)0.0254 (7)
C70.2937 (6)0.9422 (9)0.6307 (4)0.101 (4)0.60 (1)
C80.3687 (9)1.113 (1)0.7302 (6)0.146 (6)0.60 (1)
C90.2078 (9)1.163 (1)0.6271 (7)0.144 (7)0.60 (1)
C7'0.3688 (9)0.9844 (9)0.6982 (6)0.128 (8)0.40 (1)
C8'0.2113 (9)1.016 (2)0.5899 (6)0.109 (7)0.40 (1)
C9'0.275 (1)1.2007 (8)0.688 (1)0.145 (9)0.40 (1)
H10.30350.64910.57310.030*
H20.52280.55230.24340.034*
H30.44100.12860.44890.033*
H40.03600.72080.28750.034*
H50.00280.21700.46830.031*
H60.15340.27480.12990.030*
H70.24220.91310.58500.122*0.60 (1)
H810.32641.16480.77290.219*0.60 (1)
H820.42891.16630.70390.219*0.60 (1)
H830.40441.03720.76030.219*0.60 (1)
H910.15341.12140.58510.216*0.60 (1)
H920.24981.23270.59710.216*0.60 (1)
H930.16511.20020.67630.216*0.60 (1)
H7'0.41991.01230.74440.154*0.40 (1)
H81'0.25521.00220.53610.163*0.40 (1)
H82'0.14931.07900.57800.163*0.40 (1)
H83'0.17790.93240.60850.163*0.40 (1)
H91'0.25981.25570.63630.217*0.40 (1)
H92'0.34651.23030.71840.217*0.40 (1)
H93'0.21081.20710.72870.217*0.40 (1)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Co10.0151 (3)0.0245 (3)0.0221 (3)0.0003 (2)0.0024 (2)0.0034 (2)
Co20.0169 (3)0.0225 (3)0.0228 (3)0.0014 (2)0.0047 (2)0.0036 (2)
Co30.0163 (2)0.0166 (2)0.0174 (2)0.0003 (1)0.0004 (1)0.0006 (1)
Co40.0203 (2)0.0165 (2)0.0189 (2)0.0004 (2)0.0008 (2)0.0019 (1)
O10.016 (1)0.029 (1)0.022 (1)0.002 (1)0.001 (1)0.007 (1)
O20.016 (1)0.041 (1)0.042 (1)0.000 (1)0.003 (1)0.015 (1)
O30.018 (1)0.055 (2)0.025 (1)0.000 (1)0.002 (1)0.001 (1)
O40.016 (1)0.026 (1)0.024 (1)0.001 (1)0.001 (1)0.007 (1)
O50.030 (1)0.025 (1)0.039 (1)0.001 (1)0.013 (1)0.003 (1)
O60.020 (1)0.020 (1)0.026 (1)0.002 (1)0.006 (1)0.003 (1)
O70.030 (1)0.040 (1)0.031 (1)0.014 (1)0.012 (1)0.006 (1)
O80.021 (1)0.020 (1)0.025 (1)0.003 (1)0.005 (1)0.003 (1)
O90.019 (1)0.020 (1)0.028 (1)0.000 (1)0.006 (1)0.003 (1)
O100.030 (1)0.022 (1)0.028 (1)0.003 (1)0.010 (1)0.006 (1)
O110.029 (1)0.016 (1)0.020 (1)0.000 (1)0.002 (1)0.000 (1)
O120.043 (1)0.021 (1)0.024 (1)0.005 (1)0.005 (1)0.003 (1)
O130.160 (5)0.110 (4)0.142 (4)0.049 (4)0.002 (4)0.022 (3)
N10.066 (3)0.083 (3)0.060 (3)0.019 (2)0.001 (2)0.008 (2)
C10.021 (2)0.027 (2)0.026 (2)0.000 (1)0.005 (1)0.007 (1)
C20.023 (2)0.037 (2)0.026 (2)0.000 (1)0.004 (1)0.002 (1)
C30.027 (2)0.019 (2)0.036 (2)0.001 (1)0.005 (1)0.000 (1)
C40.030 (2)0.028 (2)0.027 (2)0.010 (1)0.003 (1)0.007 (1)
C50.023 (2)0.029 (2)0.026 (2)0.001 (1)0.008 (1)0.002 (1)
C60.033 (2)0.019 (1)0.024 (2)0.003 (1)0.004 (1)0.002 (1)
C70.102 (9)0.113 (9)0.087 (8)0.031 (7)0.028 (6)0.024 (6)
C80.20 (1)0.100 (9)0.14 (1)0.057 (9)0.10 (1)0.039 (8)
C90.13 (1)0.15 (1)0.15 (1)0.10 (1)0.02 (1)0.02 (1)
C7'0.20 (2)0.10 (1)0.08 (1)0.07 (1)0.057 (12)0.032 (9)
C8'0.09 (1)0.17 (2)0.060 (9)0.00 (1)0.012 (8)0.02 (1)
C9'0.10 (2)0.11 (2)0.23 (3)0.02 (1)0.00 (2)0.01 (2)
Geometric parameters (Å, º) top
Co1—O12.142 (2)O9—C51.261 (3)
Co1—O1i2.142 (2)O10—C51.235 (3)
Co1—O32.086 (2)O11—C61.272 (3)
Co1—O3i2.086 (2)O12—C61.236 (3)
Co1—O52.066 (2)O13—C71.295 (8)
Co1—O5i2.066 (2)O13—C7'1.319 (9)
Co2—O22.067 (2)N1—C71.322 (9)
Co2—O2ii2.067 (2)N1—C7'1.33 (1)
Co2—O72.080 (2)N1—C91.417 (7)
Co2—O7ii2.080 (2)N1—C9'1.415 (9)
Co2—O92.126 (2)N1—C81.432 (7)
Co2—O9ii2.126 (2)N1—C8'1.445 (8)
Co3—O12.062 (2)C1—H10.93
Co3—O42.088 (2)C2—H20.93
Co3—O62.109 (2)C3—H30.93
Co3—O82.110 (2)C4—H40.93
Co3—O92.085 (2)C5—H50.93
Co3—O112.126 (2)C6—H60.93
Co4—O4iii2.100 (2)C7—H70.93
Co4—O62.111 (2)C8—H810.96
Co4—O8iii2.116 (2)C8—H820.96
Co4—O102.055 (2)C8—H830.96
Co4—O112.108 (2)C9—H910.96
Co4—O12iii2.050 (2)C9—H920.96
O1—C11.273 (3)C9—H930.96
O2—C11.223 (3)C7'—H7'0.93
O3—C21.226 (3)C8'—H81'0.96
O4—C21.263 (4)C8'—H82'0.96
O5—C31.231 (3)C8'—H83'0.96
O6—C31.270 (3)C9'—H91'0.96
O7—C41.231 (3)C9'—H92'0.96
O8—C41.266 (3)C9'—H93'0.96
O1—Co1—O1i180C4—O7—Co2135.2 (2)
O1—Co1—O394.79 (8)C4—O8—Co3134.5 (2)
O1—Co1—O3i85.21 (8)C4—O8—Co4iv126.9 (2)
O1—Co1—O590.92 (8)Co3—O8—Co4iv98.52 (8)
O1—Co1—O5i89.08 (8)C5—O9—Co3127.9 (2)
O3—Co1—O3i180C5—O9—Co2118.2 (2)
O3—Co1—O591.50 (8)Co3—O9—Co2113.97 (8)
O3—Co1—O5i88.50 (8)C5—O10—Co4130.9 (2)
O5—Co1—O5i180C6—O11—Co4127.5 (2)
O2—Co2—O2ii180C6—O11—Co3131.8 (2)
O2—Co2—O788.55 (9)Co4—O11—Co397.61 (7)
O2—Co2—O7ii91.45 (9)C6—O12—Co4iv128.2 (2)
O4—Co3—O877.27 (7)C7—N1—C9123.8 (6)
O2—Co2—O991.90 (8)C7'—N1—C9'122.8 (8)
O2—Co2—O9ii88.10 (8)C7—N1—C8121.0 (6)
O7—Co2—O7ii180C9—N1—C8115.2 (8)
O7—Co2—O993.30 (8)C7'—N1—C8'118.9 (7)
O7—Co2—O9ii86.70 (8)C9'—N1—C8'118 (1)
O9—Co2—O9ii180O2—C1—O1126.4 (3)
O1—Co3—O995.47 (8)O3—C2—O4126.9 (3)
O1—Co3—O489.86 (8)O5—C3—O6127.1 (3)
O1—Co3—O695.48 (7)O7—C4—O8126.4 (3)
O1—Co3—O897.72 (8)O10—C5—O9127.5 (3)
O1—Co3—O11172.48 (8)O12—C6—O11126.3 (3)
O4—Co3—O694.26 (7)O13—C7—N1118.9 (6)
O4—Co3—O877.27 (7)O13—C7'—N1116.3 (7)
O4—Co3—O9170.46 (8)O2—C1—H1116.8
O4—Co3—O1187.18 (7)O1—C1—H1116.8
O6—Co3—O8164.27 (7)O3—C2—H2116.6
O6—Co3—O993.09 (7)O4—C2—H2116.6
O6—Co3—O1177.87 (7)O5—C3—H3116.4
O8—Co3—O994.14 (8)O6—C3—H3116.4
O8—Co3—O1188.38 (7)O7—C4—H4116.8
O9—Co3—O1188.44 (7)O8—C4—H4116.8
O4iii—Co4—O6172.79 (7)O10—C5—H5116.3
O4iii—Co4—O8iii76.90 (7)O9—C5—H5116.3
O4iii—Co4—O1089.55 (8)O12—C6—H6116.8
O4iii—Co4—O1194.57 (7)O11—C6—H6116.8
O4iii—Co4—O12iii94.19 (8)O13—C7—H7120.6
O6—Co4—O8iii102.80 (8)N1—C7—H7120.6
O6—Co4—O1090.40 (8)N1—C8—H81109.5
O6—Co4—O1178.22 (7)N1—C8—H82109.5
O6—Co4—O12iii93.02 (8)N1—C8—H83109.5
O8iii—Co4—O10166.32 (8)N1—C9—H91109.5
O8iii—Co4—O1188.96 (7)N1—C9—H92109.5
O8iii—Co4—O12iii90.07 (8)N1—C9—H93109.5
O10—Co4—O1190.26 (8)O13—C7'—H7'121.9
O10—Co4—O12iii92.84 (9)N1—C7'—H7'121.9
O11—Co4—O12iii170.73 (8)N1—C8'—H81'109.5
C1—O1—Co3127.4 (2)N1—C8'—H82'109.5
C1—O1—Co1117.6 (2)H81'—C8'—H82'109.5
Co3—O1—Co1114.94 (9)N1—C8'—H83'109.5
C1—O2—Co2141.1 (2)H81'—C8'—H83'109.5
C2—O3—Co1133.3 (2)H82'—C8'—H83'109.5
C2—O4—Co3132.1 (2)N1—C9'—H91'109.5
C2—O4—Co4iv127.0 (2)N1—C9'—H92'109.5
Co3—O4—Co4iv99.70 (8)H91'—C9'—H92'109.5
C3—O5—Co1133.9 (2)N1—C9'—H93'109.5
C3—O6—Co3132.6 (2)H91'—C9'—H93'109.5
C3—O6—Co4127.8 (2)H92'—C9'—H93'109.5
Co3—O6—Co498.07 (8)
O9—Co3—O1—C141.9 (2)O9—Co3—O8—Co4iv155.04 (8)
O4—Co3—O1—C1130.2 (2)O4—Co3—O8—Co4iv20.75 (8)
O6—Co3—O1—C1135.5 (2)O6—Co3—O8—Co4iv37.9 (3)
O8—Co3—O1—C153.0 (2)O11—Co3—O8—Co4iv66.72 (8)
O9—Co3—O1—Co1134.6 (1)O1—Co3—O9—C5129.1 (2)
O4—Co3—O1—Co153.3 (1)O6—Co3—O9—C533.3 (2)
O6—Co3—O1—Co141.0 (1)O8—Co3—O9—C5132.7 (2)
O8—Co3—O1—Co1130.42 (9)O11—Co3—O9—C544.4 (2)
O5—Co1—O1—C1125.0 (2)O1—Co3—O9—Co251.9 (1)
O5i—Co1—O1—C155.0 (2)O6—Co3—O9—Co2147.73 (9)
O3—Co1—O1—C1143.4 (2)O8—Co3—O9—Co246.3 (1)
O3i—Co1—O1—C136.6 (2)O11—Co3—O9—Co2134.5 (1)
O5—Co1—O1—Co351.9 (1)O2—Co2—O9—C5141.4 (2)
O5i—Co1—O1—Co3128.1 (1)O2ii—Co2—O9—C538.6 (2)
O3—Co1—O1—Co339.7 (1)O7—Co2—O9—C5129.9 (2)
O3i—Co1—O1—Co3140.3 (1)O7ii—Co2—O9—C550.1 (2)
O7—Co2—O2—C185.9 (4)O2—Co2—O9—Co339.6 (1)
O7ii—Co2—O2—C194.1 (4)O2ii—Co2—O9—Co3140.5 (1)
O9—Co2—O2—C17.4 (4)O7—Co2—O9—Co349.1 (1)
O9ii—Co2—O2—C1172.6 (4)O7ii—Co2—O9—Co3130.9 (1)
O5—Co1—O3—C292.7 (3)O12iii—Co4—O10—C5136.7 (3)
O5i—Co1—O3—C287.3 (3)O4iii—Co4—O10—C5129.2 (3)
O1i—Co1—O3—C2178.4 (3)O11—Co4—O10—C534.6 (3)
O1—Co1—O3—C21.6 (3)O6—Co4—O10—C543.6 (3)
O1—Co3—O4—C249.1 (3)O8iii—Co4—O10—C5121.3 (3)
O6—Co3—O4—C246.3 (3)O10—Co4—O11—C6129.5 (2)
O8—Co3—O4—C2147.1 (3)O4iii—Co4—O11—C639.9 (2)
O11—Co3—O4—C2123.9 (3)O6—Co4—O11—C6140.2 (2)
O1—Co3—O4—Co4iv118.93 (8)O8iii—Co4—O11—C636.9 (2)
O6—Co3—O4—Co4iv145.59 (8)O10—Co4—O11—Co368.82 (8)
O8—Co3—O4—Co4iv20.99 (8)O4iii—Co4—O11—Co3158.39 (8)
O11—Co3—O4—Co4iv67.98 (8)O6—Co4—O11—Co321.53 (8)
O3—Co1—O5—C352.7 (3)O8iii—Co4—O11—Co3124.84 (8)
O3i—Co1—O5—C3127.3 (3)O9—Co3—O11—C6127.6 (3)
O1i—Co1—O5—C3137.9 (3)O4—Co3—O11—C643.9 (3)
O1—Co1—O5—C342.1 (3)O6—Co3—O11—C6138.9 (3)
O1—Co3—O6—C34.6 (3)O8—Co3—O11—C633.4 (3)
O9—Co3—O6—C3100.4 (3)O9—Co3—O11—Co471.92 (8)
O4—Co3—O6—C385.7 (3)O4—Co3—O11—Co4116.55 (8)
O8—Co3—O6—C3142.3 (3)O6—Co3—O11—Co421.58 (8)
O11—Co3—O6—C3171.9 (3)O8—Co3—O11—Co4166.11 (8)
O1—Co3—O6—Co4161.96 (8)Co2—O2—C1—O18.4 (6)
O9—Co3—O6—Co466.16 (8)Co3—O1—C1—O213.6 (5)
O4—Co3—O6—Co4107.77 (8)Co1—O1—C1—O2162.9 (3)
O8—Co3—O6—Co451.1 (3)Co1—O3—C2—O417.1 (5)
O11—Co3—O6—Co421.58 (7)Co3—O4—C2—O315.3 (5)
O12iii—Co4—O6—C36.2 (2)Co4iv—O4—C2—O3149.9 (3)
O10—Co4—O6—C399.0 (2)Co1—O5—C3—O610.4 (5)
O11—Co4—O6—C3170.8 (2)Co3—O6—C3—O514.7 (5)
O8iii—Co4—O6—C384.6 (2)Co4—O6—C3—O5177.7 (2)
O12iii—Co4—O6—Co3161.31 (8)Co2—O7—C4—O85.4 (5)
O10—Co4—O6—Co368.45 (8)Co3—O8—C4—O70.8 (5)
O11—Co4—O6—Co321.74 (7)Co4iv—O8—C4—O7176.8 (2)
O8iii—Co4—O6—Co3107.93 (8)Co4—O10—C5—O93.2 (5)
O2—Co2—O7—C461.1 (3)Co3—O9—C5—O103.2 (5)
O2ii—Co2—O7—C4118.9 (3)Co2—O9—C5—O10175.7 (2)
O9—Co2—O7—C430.7 (3)Co4iv—O12—C6—O115.3 (5)
O9ii—Co2—O7—C4149.3 (3)Co4—O11—C6—O12152.7 (2)
O1—Co3—O8—C474.4 (3)Co3—O11—C6—O122.6 (5)
O9—Co3—O8—C421.7 (3)C9—N1—C7—O13179.9 (3)
O4—Co3—O8—C4162.5 (3)C8—N1—C7—O130.8 (3)
O6—Co3—O8—C4138.8 (3)C9'—N1—C7'—O13179.8 (4)
O11—Co3—O8—C4110.0 (3)C8'—N1—C7'—O130.8 (7)
O1—Co3—O8—Co4iv108.85 (8)
Symmetry codes: (i) x+1, y+1, z+1; (ii) x, y+1, z+1; (iii) x+1/2, y1/2, z+1/2; (iv) x+1/2, y+1/2, z+1/2.
 

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