Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805006008/hb6159sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536805006008/hb6159Isup2.hkl |
CCDC reference: 270327
Key indicators
- Single-crystal X-ray study
- T = 110 K
- Mean (C-C) = 0.003 Å
- R factor = 0.033
- wR factor = 0.084
- Data-to-parameter ratio = 22.8
checkCIF/PLATON results
No syntax errors found
Alert level C WEIGH01_ALERT_1_C Extra text has been found in the _refine_ls_weighting_scheme field. This should be in the _refine_ls_weighting_details field. Weighting scheme given as calc w = 1/[\s^2^(Fo^2^)+(0.0411P)^2^] where Weighting scheme identified as calc PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.75 Ratio PLAT220_ALERT_2_C Large Non-Solvent O Ueq(max)/Ueq(min) ... 2.50 Ratio PLAT230_ALERT_2_C Hirshfeld Test Diff for O3 - C3 .. 5.97 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Cr1 - C1 .. 7.22 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Cr1 - C2 .. 5.50 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Cr1 - C3 .. 8.52 su
Alert level G REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is correct. If it is not, please give the correct count in the _publ_section_exptl_refinement section of the submitted CIF. From the CIF: _diffrn_reflns_theta_max 28.34 From the CIF: _reflns_number_total 5984 Count of symmetry unique reflns 3406 Completeness (_total/calc) 175.69% TEST3: Check Friedels for noncentro structure Estimate of Friedel pairs measured 2578 Fraction of Friedel pairs measured 0.757 Are heavy atom types Z>Si present yes
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 7 ALERT level C = Check and explain 1 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 6 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: SMART (Bruker, 2001); cell refinement: SAINT-Plus (Bruker, 1999); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: PLATON (Spek, 1990); software used to prepare material for publication: SHELXL97.
[Cr(C17H33NOSi2)(CO)3] | F(000) = 976 |
Mr = 459.65 | Dx = 1.269 Mg m−3 |
Orthorhombic, P212121 | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: P 2ac 2ab | Cell parameters from 8096 reflections |
a = 7.1361 (12) Å | θ = 1.6–28.3° |
b = 17.251 (3) Å | µ = 0.60 mm−1 |
c = 19.541 (3) Å | T = 110 K |
V = 2405.7 (7) Å3 | Rod, yellow |
Z = 4 | 0.44 × 0.03 × 0.03 mm |
Bruker SMART APEX CCD diffractometer | 5984 independent reflections |
Radiation source: fine-focus sealed tube | 5037 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.071 |
ω scans | θmax = 28.3°, θmin = 1.6° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −9→9 |
Tmin = 0.779, Tmax = 0.982 | k = −22→22 |
33064 measured reflections | l = −26→26 |
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.033 | H-atom parameters constrained |
wR(F2) = 0.084 | Calculated w = 1/[σ2(Fo2) + (0.0411P)2] where P = (Fo2 + 2Fc2)/3 |
S = 0.92 | (Δ/σ)max = 0.001 |
5984 reflections | Δρmax = 0.38 e Å−3 |
263 parameters | Δρmin = −0.28 e Å−3 |
0 restraints | Absolute structure: Flack (1983), 2578 Friedel pairs |
Primary atom site location: structure-invariant direct methods | Absolute structure parameter: −0.006 (18) |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Cr1 | 0.98443 (5) | 0.45762 (2) | 0.84988 (2) | 0.01594 (10) | |
Si1 | 1.17726 (11) | 0.27393 (4) | 0.78356 (4) | 0.02093 (17) | |
C3 | 0.8465 (4) | 0.54734 (16) | 0.85956 (13) | 0.0229 (6) | |
C1 | 0.9031 (4) | 0.45942 (18) | 0.75998 (14) | 0.0257 (6) | |
O1 | 0.8477 (3) | 0.46077 (14) | 0.70419 (10) | 0.0418 (6) | |
O3 | 0.7551 (3) | 0.60341 (11) | 0.86346 (10) | 0.0352 (5) | |
O4 | 1.0690 (2) | 0.30018 (10) | 0.93887 (8) | 0.0167 (4) | |
C111 | 0.8744 (3) | 0.46147 (16) | 1.03395 (13) | 0.0199 (5) | |
H11A | 0.8388 | 0.4576 | 1.0823 | 0.026* | |
H11B | 0.7903 | 0.4293 | 1.0063 | 0.026* | |
H11C | 0.8649 | 0.5156 | 1.0191 | 0.026* | |
C112 | 1.0769 (3) | 0.43323 (14) | 1.02488 (13) | 0.0151 (5) | |
H112 | 1.0816 | 0.3788 | 1.0392 | 0.020* | |
O2 | 0.6397 (3) | 0.36598 (13) | 0.88574 (10) | 0.0345 (5) | |
C108 | 1.1403 (3) | 0.43711 (13) | 0.94965 (12) | 0.0135 (5) | |
C107 | 1.2075 (3) | 0.50808 (14) | 0.91974 (12) | 0.0154 (5) | |
C104 | 1.2014 (3) | 0.36392 (14) | 0.84005 (12) | 0.0160 (5) | |
N | 1.2153 (3) | 0.47627 (12) | 1.06621 (10) | 0.0162 (4) | |
C2 | 0.7720 (4) | 0.40155 (16) | 0.87113 (13) | 0.0243 (6) | |
C106 | 1.2772 (3) | 0.50371 (14) | 0.85110 (13) | 0.0172 (5) | |
H106 | 1.3299 | 0.5504 | 0.8299 | 0.022* | |
C114 | 1.1591 (4) | 0.48355 (16) | 1.13858 (12) | 0.0236 (6) | |
H11D | 1.0472 | 0.5163 | 1.1419 | 0.031* | |
H11E | 1.2614 | 0.5072 | 1.1648 | 0.031* | |
H11F | 1.1314 | 0.4320 | 1.1572 | 0.031* | |
C109 | 1.1403 (3) | 0.36762 (14) | 0.90924 (12) | 0.0145 (5) | |
C101 | 1.2286 (5) | 0.30497 (16) | 0.69358 (14) | 0.0318 (7) | |
H10A | 1.3594 | 0.3218 | 0.6903 | 0.041* | |
H10B | 1.1457 | 0.3480 | 0.6810 | 0.041* | |
H10C | 1.2075 | 0.2613 | 0.6624 | 0.041* | |
C103 | 0.9352 (4) | 0.23323 (18) | 0.78814 (14) | 0.0316 (7) | |
H10D | 0.8487 | 0.2673 | 0.7633 | 0.041* | |
H10E | 0.8962 | 0.2295 | 0.8361 | 0.041* | |
H10F | 0.9335 | 0.1815 | 0.7674 | 0.041* | |
C110 | 1.2124 (4) | 0.25447 (15) | 0.97172 (13) | 0.0219 (6) | |
H11G | 1.3255 | 0.2543 | 0.9432 | 0.028* | |
H11H | 1.1675 | 0.2012 | 0.9777 | 0.028* | |
H11I | 1.2417 | 0.2769 | 1.0165 | 0.028* | |
C105 | 1.2723 (3) | 0.43419 (14) | 0.81309 (12) | 0.0172 (5) | |
H105 | 1.3201 | 0.4346 | 0.7661 | 0.022* | |
C113 | 1.3967 (3) | 0.43617 (15) | 1.06444 (13) | 0.0204 (6) | |
H11J | 1.4396 | 0.4319 | 1.0170 | 0.027* | |
H11K | 1.3829 | 0.3842 | 1.0841 | 0.027* | |
H11L | 1.4886 | 0.4656 | 1.0911 | 0.027* | |
C102 | 1.3528 (5) | 0.19796 (17) | 0.80738 (16) | 0.0372 (8) | |
H10G | 1.3622 | 0.1597 | 0.7704 | 0.048* | |
H10H | 1.3129 | 0.1721 | 0.8496 | 0.048* | |
H10I | 1.4754 | 0.2223 | 0.8146 | 0.048* | |
Si2 | 1.23779 (10) | 0.60869 (4) | 0.96241 (4) | 0.01796 (15) | |
C115 | 1.4685 (4) | 0.61550 (15) | 1.00738 (13) | 0.0248 (6) | |
H11M | 1.5084 | 0.6698 | 1.0092 | 0.032* | |
H11N | 1.5622 | 0.5850 | 0.9825 | 0.032* | |
H11O | 1.4558 | 0.5952 | 1.0540 | 0.032* | |
C116 | 1.2506 (5) | 0.67954 (15) | 0.88914 (14) | 0.0281 (6) | |
H11P | 1.2451 | 0.7326 | 0.9070 | 0.036* | |
H11Q | 1.1448 | 0.6708 | 0.8581 | 0.036* | |
H11R | 1.3684 | 0.6721 | 0.8642 | 0.036* | |
C117 | 1.0440 (4) | 0.64717 (15) | 1.01782 (14) | 0.0241 (6) | |
H11S | 1.0326 | 0.6150 | 1.0589 | 0.031* | |
H11T | 0.9258 | 0.6460 | 0.9923 | 0.031* | |
H11U | 1.0725 | 0.7007 | 1.0311 | 0.031* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Cr1 | 0.0155 (2) | 0.01745 (19) | 0.01493 (18) | 0.00097 (18) | −0.00227 (17) | 0.00342 (17) |
Si1 | 0.0294 (4) | 0.0177 (4) | 0.0158 (4) | −0.0003 (3) | −0.0012 (3) | −0.0003 (3) |
C3 | 0.0228 (13) | 0.0263 (14) | 0.0197 (13) | −0.0021 (13) | −0.0030 (11) | 0.0027 (12) |
C1 | 0.0209 (13) | 0.0318 (15) | 0.0244 (14) | 0.0034 (13) | −0.0005 (11) | 0.0030 (13) |
O1 | 0.0365 (12) | 0.0668 (16) | 0.0220 (11) | 0.0052 (13) | −0.0087 (9) | 0.0041 (11) |
O3 | 0.0327 (11) | 0.0291 (11) | 0.0437 (13) | 0.0150 (10) | −0.0011 (10) | 0.0034 (10) |
O4 | 0.0183 (9) | 0.0148 (9) | 0.0169 (9) | −0.0015 (7) | −0.0028 (7) | 0.0038 (7) |
C111 | 0.0152 (12) | 0.0234 (13) | 0.0210 (13) | −0.0026 (11) | 0.0004 (10) | −0.0007 (12) |
C112 | 0.0165 (12) | 0.0131 (12) | 0.0156 (12) | 0.0003 (10) | 0.0008 (10) | 0.0003 (10) |
O2 | 0.0199 (11) | 0.0421 (13) | 0.0416 (13) | −0.0063 (10) | −0.0052 (9) | 0.0160 (10) |
C108 | 0.0116 (11) | 0.0143 (12) | 0.0146 (12) | 0.0022 (9) | −0.0031 (9) | 0.0009 (9) |
C107 | 0.0124 (12) | 0.0157 (12) | 0.0180 (13) | 0.0006 (10) | −0.0017 (10) | 0.0015 (10) |
C104 | 0.0154 (12) | 0.0169 (12) | 0.0157 (12) | 0.0012 (10) | −0.0017 (10) | 0.0007 (10) |
N | 0.0149 (10) | 0.0202 (11) | 0.0137 (10) | 0.0009 (9) | 0.0002 (8) | −0.0012 (8) |
C2 | 0.0216 (14) | 0.0274 (15) | 0.0240 (14) | 0.0009 (13) | −0.0063 (11) | 0.0078 (12) |
C106 | 0.0150 (12) | 0.0167 (12) | 0.0199 (12) | −0.0013 (10) | −0.0011 (11) | 0.0042 (11) |
C114 | 0.0246 (14) | 0.0308 (15) | 0.0155 (13) | −0.0018 (12) | 0.0020 (11) | −0.0042 (11) |
C109 | 0.0099 (11) | 0.0155 (12) | 0.0181 (12) | 0.0006 (10) | −0.0031 (10) | 0.0032 (10) |
C101 | 0.053 (2) | 0.0226 (15) | 0.0202 (14) | −0.0036 (15) | 0.0048 (14) | −0.0045 (12) |
C103 | 0.0401 (18) | 0.0327 (17) | 0.0220 (15) | −0.0094 (14) | −0.0048 (13) | −0.0016 (13) |
C110 | 0.0241 (15) | 0.0181 (13) | 0.0234 (14) | 0.0025 (11) | 0.0004 (11) | 0.0052 (11) |
C105 | 0.0146 (12) | 0.0220 (13) | 0.0149 (12) | 0.0017 (10) | −0.0001 (10) | 0.0028 (10) |
C113 | 0.0161 (13) | 0.0246 (14) | 0.0207 (13) | 0.0026 (11) | −0.0048 (10) | 0.0002 (11) |
C102 | 0.050 (2) | 0.0285 (17) | 0.0328 (17) | 0.0128 (15) | −0.0065 (16) | −0.0111 (14) |
Si2 | 0.0197 (4) | 0.0150 (3) | 0.0192 (4) | −0.0006 (3) | −0.0015 (3) | 0.0007 (3) |
C115 | 0.0235 (15) | 0.0214 (14) | 0.0296 (15) | −0.0055 (12) | −0.0030 (12) | 0.0008 (11) |
C116 | 0.0387 (17) | 0.0172 (13) | 0.0282 (15) | −0.0046 (13) | −0.0065 (14) | 0.0014 (11) |
C117 | 0.0240 (16) | 0.0185 (13) | 0.0299 (15) | 0.0030 (11) | 0.0006 (12) | −0.0022 (11) |
Cr1—C3 | 1.844 (3) | C106—C105 | 1.411 (3) |
Cr1—C2 | 1.846 (3) | C106—H106 | 0.9800 |
Cr1—C1 | 1.850 (3) | C114—H11D | 0.9801 |
Cr1—C105 | 2.214 (3) | C114—H11E | 0.9801 |
Cr1—C109 | 2.235 (2) | C114—H11F | 0.9801 |
Cr1—C106 | 2.236 (2) | C101—H10A | 0.9801 |
Cr1—C104 | 2.246 (2) | C101—H10B | 0.9801 |
Cr1—C107 | 2.270 (2) | C101—H10C | 0.9801 |
Cr1—C108 | 2.272 (2) | C103—H10D | 0.9801 |
Si1—C103 | 1.867 (3) | C103—H10E | 0.9801 |
Si1—C102 | 1.872 (3) | C103—H10F | 0.9801 |
Si1—C101 | 1.874 (3) | C110—H11G | 0.9801 |
Si1—C104 | 1.913 (3) | C110—H11H | 0.9801 |
C3—O3 | 1.169 (3) | C110—H11I | 0.9801 |
C1—O1 | 1.160 (3) | C105—H105 | 0.9800 |
O4—C109 | 1.396 (3) | C113—H11J | 0.9801 |
O4—C110 | 1.443 (3) | C113—H11K | 0.9801 |
C111—C112 | 1.535 (3) | C113—H11L | 0.9801 |
C111—H11A | 0.9801 | C102—H10G | 0.9801 |
C111—H11B | 0.9801 | C102—H10H | 0.9801 |
C111—H11C | 0.9801 | C102—H10I | 0.9801 |
C112—N | 1.476 (3) | Si2—C115 | 1.870 (3) |
C112—C108 | 1.540 (3) | Si2—C117 | 1.877 (3) |
C112—H112 | 0.9800 | Si2—C116 | 1.885 (3) |
O2—C2 | 1.162 (3) | C115—H11M | 0.9801 |
C108—C109 | 1.435 (3) | C115—H11N | 0.9801 |
C108—C107 | 1.439 (3) | C115—H11O | 0.9801 |
C107—C106 | 1.433 (3) | C116—H11P | 0.9801 |
C107—Si2 | 1.938 (3) | C116—H11Q | 0.9801 |
C104—C105 | 1.415 (3) | C116—H11R | 0.9801 |
C104—C109 | 1.422 (3) | C117—H11S | 0.9801 |
N—C113 | 1.468 (3) | C117—H11T | 0.9801 |
N—C114 | 1.475 (3) | C117—H11U | 0.9801 |
C3—Cr1—C2 | 88.76 (12) | C105—C106—C107 | 121.9 (2) |
C3—Cr1—C1 | 85.17 (12) | C105—C106—Cr1 | 70.67 (14) |
C2—Cr1—C1 | 87.98 (12) | C107—C106—Cr1 | 72.78 (13) |
C3—Cr1—C105 | 133.00 (11) | C105—C106—H106 | 119.0 |
C2—Cr1—C105 | 137.70 (11) | C107—C106—H106 | 119.0 |
C1—Cr1—C105 | 89.19 (10) | Cr1—C106—H106 | 130.2 |
C3—Cr1—C109 | 142.72 (10) | N—C114—H11D | 109.5 |
C2—Cr1—C109 | 85.86 (10) | N—C114—H11E | 109.5 |
C1—Cr1—C109 | 131.35 (11) | H11D—C114—H11E | 109.5 |
C105—Cr1—C109 | 65.16 (9) | N—C114—H11F | 109.5 |
C3—Cr1—C106 | 101.50 (10) | H11D—C114—H11F | 109.5 |
C2—Cr1—C106 | 162.11 (10) | H11E—C114—H11F | 109.5 |
C1—Cr1—C106 | 107.30 (11) | O4—C109—C104 | 118.0 (2) |
C105—Cr1—C106 | 36.97 (9) | O4—C109—C108 | 117.9 (2) |
C109—Cr1—C106 | 77.08 (9) | C104—C109—C108 | 124.1 (2) |
C3—Cr1—C104 | 168.71 (10) | O4—C109—Cr1 | 127.82 (16) |
C2—Cr1—C104 | 102.01 (11) | C104—C109—Cr1 | 71.95 (13) |
C1—Cr1—C104 | 98.45 (11) | C108—C109—Cr1 | 72.87 (13) |
C105—Cr1—C104 | 37.00 (9) | Si1—C101—H10A | 109.5 |
C109—Cr1—C104 | 37.01 (8) | Si1—C101—H10B | 109.5 |
C106—Cr1—C104 | 67.22 (9) | H10A—C101—H10B | 109.5 |
C3—Cr1—C107 | 89.48 (10) | Si1—C101—H10C | 109.5 |
C2—Cr1—C107 | 129.91 (10) | H10A—C101—H10C | 109.5 |
C1—Cr1—C107 | 141.65 (11) | H10B—C101—H10C | 109.5 |
C105—Cr1—C107 | 67.33 (9) | Si1—C103—H10D | 109.5 |
C109—Cr1—C107 | 66.76 (9) | Si1—C103—H10E | 109.5 |
C106—Cr1—C107 | 37.07 (9) | H10D—C103—H10E | 109.5 |
C104—Cr1—C107 | 81.04 (9) | Si1—C103—H10F | 109.5 |
C3—Cr1—C108 | 107.71 (10) | H10D—C103—H10F | 109.5 |
C2—Cr1—C108 | 97.33 (10) | H10E—C103—H10F | 109.5 |
C1—Cr1—C108 | 166.09 (10) | O4—C110—H11G | 109.5 |
C105—Cr1—C108 | 78.22 (9) | O4—C110—H11H | 109.5 |
C109—Cr1—C108 | 37.13 (8) | H11G—C110—H11H | 109.5 |
C106—Cr1—C108 | 65.71 (9) | O4—C110—H11I | 109.5 |
C104—Cr1—C108 | 67.91 (9) | H11G—C110—H11I | 109.5 |
C107—Cr1—C108 | 36.93 (8) | H11H—C110—H11I | 109.5 |
C103—Si1—C102 | 110.13 (15) | C106—C105—C104 | 122.7 (2) |
C103—Si1—C101 | 109.48 (14) | C106—C105—Cr1 | 72.35 (14) |
C102—Si1—C101 | 107.61 (15) | C104—C105—Cr1 | 72.75 (14) |
C103—Si1—C104 | 111.14 (12) | C106—C105—H105 | 118.6 |
C102—Si1—C104 | 111.38 (12) | C104—C105—H105 | 118.6 |
C101—Si1—C104 | 106.98 (12) | Cr1—C105—H105 | 128.7 |
O3—C3—Cr1 | 177.4 (2) | N—C113—H11J | 109.5 |
O1—C1—Cr1 | 178.3 (2) | N—C113—H11K | 109.5 |
C109—O4—C110 | 112.43 (18) | H11J—C113—H11K | 109.5 |
C112—C111—H11A | 109.5 | N—C113—H11L | 109.5 |
C112—C111—H11B | 109.5 | H11J—C113—H11L | 109.5 |
H11A—C111—H11B | 109.5 | H11K—C113—H11L | 109.5 |
C112—C111—H11C | 109.5 | Si1—C102—H10G | 109.5 |
H11A—C111—H11C | 109.5 | Si1—C102—H10H | 109.5 |
H11B—C111—H11C | 109.5 | H10G—C102—H10H | 109.5 |
N—C112—C111 | 114.0 (2) | Si1—C102—H10I | 109.5 |
N—C112—C108 | 107.70 (19) | H10G—C102—H10I | 109.5 |
C111—C112—C108 | 111.9 (2) | H10H—C102—H10I | 109.5 |
N—C112—H112 | 107.7 | C115—Si2—C117 | 110.81 (12) |
C111—C112—H112 | 107.7 | C115—Si2—C116 | 105.88 (13) |
C108—C112—H112 | 107.7 | C117—Si2—C116 | 104.16 (13) |
C109—C108—C107 | 119.2 (2) | C115—Si2—C107 | 110.90 (11) |
C109—C108—C112 | 119.3 (2) | C117—Si2—C107 | 118.86 (12) |
C107—C108—C112 | 121.5 (2) | C116—Si2—C107 | 105.03 (11) |
C109—C108—Cr1 | 70.00 (13) | Si2—C115—H11M | 109.5 |
C107—C108—Cr1 | 71.46 (13) | Si2—C115—H11N | 109.5 |
C112—C108—Cr1 | 133.00 (16) | H11M—C115—H11N | 109.5 |
C106—C107—C108 | 116.8 (2) | Si2—C115—H11O | 109.5 |
C106—C107—Si2 | 114.29 (17) | H11M—C115—H11O | 109.5 |
C108—C107—Si2 | 128.66 (18) | H11N—C115—H11O | 109.5 |
C106—C107—Cr1 | 70.15 (13) | Si2—C116—H11P | 109.5 |
C108—C107—Cr1 | 71.61 (13) | Si2—C116—H11Q | 109.5 |
Si2—C107—Cr1 | 132.88 (12) | H11P—C116—H11Q | 109.5 |
C105—C104—C109 | 115.2 (2) | Si2—C116—H11R | 109.5 |
C105—C104—Si1 | 120.83 (18) | H11P—C116—H11R | 109.5 |
C109—C104—Si1 | 123.89 (18) | H11Q—C116—H11R | 109.5 |
C105—C104—Cr1 | 70.26 (14) | Si2—C117—H11S | 109.5 |
C109—C104—Cr1 | 71.04 (13) | Si2—C117—H11T | 109.5 |
Si1—C104—Cr1 | 124.86 (12) | H11S—C117—H11T | 109.5 |
C113—N—C114 | 107.59 (19) | Si2—C117—H11U | 109.5 |
C113—N—C112 | 109.87 (19) | H11S—C117—H11U | 109.5 |
C114—N—C112 | 112.7 (2) | H11T—C117—H11U | 109.5 |
O2—C2—Cr1 | 178.7 (2) |