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Acta Cryst. (2005). E61, m635-m637  [ doi:10.1107/S1600536805005957 ]

catena-Poly[diaquazinc(II)-[mu]-(diethyl dichloromethylenebisphosphonato)-[kappa]3O,O':O''-tetraaquazinc(II)-[mu]-(diethyl dichloromethylenebisphosphonato)-[kappa]3O:O',O'']

M. Kontturi, S. Peräniemi, J. J. Vepsäläinen and M. Ahlgrén

Abstract: The title structure, [Zn(C5H10Cl2O6P2)(H2O)3]n, consists of one-dimensional chains. The structure is best described as centrosymmetric monomeric units consisting of octahedral Zn atoms with two symmetrically chelating [Cl2C(PO3Et)2]2- ligands, connected into polymeric chains along the [110] direction by further octahedral Zn atoms.

Online 4 March 2005


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