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Acta Cryst. (2005). E61, m616-m618 [ doi:10.1107/S1600536805005866 ]
![[mu]](/logos/entities/mu_rmgif.gif)
2-azido-![[kappa]](/logos/entities/kappa_rmgif.gif)
2N1:N1-3-nicotinato-3N:O:O']Abstract: The title complex, [Zn(N3)(C6H4NO2)]n, formed from Zn cations, nicotinate and azide groups, exhibits a three-dimensional non-centrosymmetric covalent network. The coordination sphere of the central metal ions is completed by an N3O2 five-coordinate coordination model showing distorted trigonal-bipyramidal geometry. Adjacent Zn atoms are bonded by 2-carboxylate groups and a 2-azide bridge into one-dimensional helical double-stranded chains with the six-membered ring running along the a axis, and these chains are further linked by 3-nicotinate groups via covalent bonds, extending into two-dimensional sheets and further generating a non-centrosymmetric three-dimensional covalent network.
Online 4 March 2005
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