The title compound, [Ag2(C7H4NO4)2(C4H10N2)]·H2O, has two similar dinuclear AgI complex molecules, each with a crystallographic inversion center; the asymmetric unit contains half of each molecule and a molecule of water. Each Ag atom in the compound is coordinated by one O atom from a 3-nitrobenzoate anion and one N atom from a piperidine bridge, in a slightly distorted linear geometry.
Supporting information
CCDC reference: 270509
Key indicators
- Single-crystal X-ray study
- T = 298 K
- Mean (C-C) = 0.007 Å
- R factor = 0.051
- wR factor = 0.115
- Data-to-parameter ratio = 14.6
checkCIF/PLATON results
No syntax errors found
Alert level B
PLAT731_ALERT_1_B Bond Calc 0.84(5), Rep 0.841(10) ...... 5.00 su-Rat
O9 -H1 1.555 1.555
PLAT731_ALERT_1_B Bond Calc 0.89(5), Rep 0.897(10) ...... 5.00 su-Rat
N4 -H4A 1.555 1.555
PLAT735_ALERT_1_B D-H Calc 0.89(5), Rep 0.897(10) ...... 5.00 su-Rat
N4 -H4A 1.555 1.555
PLAT735_ALERT_1_B D-H Calc 0.84(5), Rep 0.841(10) ...... 5.00 su-Rat
O9 -H1 1.555 1.555
PLAT736_ALERT_1_B H...A Calc 1.91(5), Rep 1.905(12) ...... 4.17 su-Rat
H1 -O6 1.555 1.555
Alert level C
PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given ....... ?
PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for N3
PLAT731_ALERT_1_C Bond Calc 0.84(4), Rep 0.841(10) ...... 4.00 su-Rat
O9 -H2 1.555 1.555
PLAT731_ALERT_1_C Bond Calc 0.90(3), Rep 0.895(10) ...... 3.00 su-Rat
N2 -H2A 1.555 1.555
PLAT735_ALERT_1_C D-H Calc 0.90(3), Rep 0.895(10) ...... 3.00 su-Rat
N2 -H2A 1.555 1.555
PLAT735_ALERT_1_C D-H Calc 0.84(4), Rep 0.841(10) ...... 4.00 su-Rat
O9 -H2 1.555 1.555
PLAT736_ALERT_1_C H...A Calc 2.10(5), Rep 2.094(19) ...... 2.63 su-Rat
H4A -O6 1.555 3.656
0 ALERT level A = In general: serious problem
5 ALERT level B = Potentially serious problem
7 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
10 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
1 ALERT type 2 Indicator that the structure model may be wrong or deficient
0 ALERT type 3 Indicator that the structure quality may be low
1 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: SMART (Siemens, 1996); cell refinement: SMART (Siemens, 1996); data reduction: SAINT (Siemens, 1996); program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick, 1997); software used to prepare material for publication: SHELXTL.
µ-Piperidine-
κ2N:
N'-bis[(3-nitrobenzoato-
κO)silver(I)]
monohydrate
top
Crystal data top
[Ag2(C7H4NO4)2(C4H10N2)]·H2O | F(000) = 1288 |
Mr = 652.12 | Dx = 2.052 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
a = 7.285 (1) Å | Cell parameters from 2560 reflections |
b = 24.298 (2) Å | θ = 2.4–25.8° |
c = 11.945 (1) Å | µ = 1.92 mm−1 |
β = 93.523 (2)° | T = 298 K |
V = 2110.4 (4) Å3 | Block, yellow |
Z = 4 | 0.37 × 0.25 × 0.14 mm |
Data collection top
Bruker SMART CCD area-detector diffractometer | 4571 independent reflections |
Radiation source: fine-focus sealed tube | 3873 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.030 |
ω scans | θmax = 27.0°, θmin = 1.7° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −9→9 |
Tmin = 0.532, Tmax = 0.767 | k = −30→30 |
17019 measured reflections | l = −15→15 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.051 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.115 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.05 | w = 1/[σ2(Fo2) + (0.0377P)2 + 6.6578P] where P = (Fo2 + 2Fc2)/3 |
4571 reflections | (Δ/σ)max < 0.001 |
314 parameters | Δρmax = 2.03 e Å−3 |
5 restraints | Δρmin = −1.90 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Ag1 | 0.68212 (6) | 0.074743 (16) | 0.95235 (4) | 0.05264 (14) | |
Ag2 | 0.66994 (6) | 0.068490 (17) | 0.50907 (5) | 0.07046 (18) | |
O1 | 0.5335 (6) | 0.14164 (15) | 0.8805 (3) | 0.0614 (10) | |
O2 | 0.4446 (8) | 0.09671 (16) | 0.7235 (4) | 0.0888 (16) | |
O3 | 0.4740 (6) | 0.33842 (17) | 0.8990 (4) | 0.0714 (12) | |
O4 | 0.3434 (6) | 0.38385 (15) | 0.7614 (4) | 0.0700 (12) | |
O5 | 0.5455 (6) | 0.13970 (15) | 0.4327 (3) | 0.0609 (10) | |
O6 | 0.3836 (6) | 0.08316 (14) | 0.3169 (4) | 0.0753 (13) | |
O7 | 0.4811 (6) | 0.33634 (15) | 0.3761 (4) | 0.0732 (12) | |
O8 | 0.3892 (7) | 0.36857 (17) | 0.2163 (4) | 0.0887 (15) | |
O9 | 0.5298 (7) | 0.00414 (18) | 0.1843 (4) | 0.0701 (12) | |
N1 | 0.3969 (6) | 0.34084 (16) | 0.8058 (4) | 0.0485 (10) | |
N2 | 0.8497 (5) | 0.02088 (15) | 1.0581 (3) | 0.0354 (8) | |
N3 | 0.4204 (6) | 0.33031 (16) | 0.2800 (4) | 0.0511 (10) | |
N4 | 0.8345 (6) | −0.00314 (17) | 0.5585 (4) | 0.0504 (10) | |
C1 | 0.4602 (7) | 0.1386 (2) | 0.7824 (5) | 0.0513 (12) | |
C2 | 0.3922 (6) | 0.19242 (18) | 0.7321 (4) | 0.0363 (9) | |
C3 | 0.3108 (6) | 0.1945 (2) | 0.6249 (4) | 0.0434 (11) | |
H3 | 0.2912 | 0.1621 | 0.5845 | 0.052* | |
C4 | 0.2579 (6) | 0.2443 (2) | 0.5771 (4) | 0.0466 (11) | |
H4 | 0.2026 | 0.2449 | 0.5048 | 0.056* | |
C5 | 0.2855 (6) | 0.2926 (2) | 0.6343 (4) | 0.0441 (11) | |
H5 | 0.2517 | 0.3262 | 0.6017 | 0.053* | |
C6 | 0.3655 (6) | 0.28982 (18) | 0.7424 (4) | 0.0350 (9) | |
C7 | 0.4178 (6) | 0.24085 (18) | 0.7927 (4) | 0.0348 (9) | |
H7 | 0.4693 | 0.2402 | 0.8659 | 0.042* | |
C8 | 1.0395 (7) | 0.0396 (2) | 1.0840 (4) | 0.0494 (12) | |
H8A | 1.0975 | 0.0165 | 1.1423 | 0.059* | |
H8B | 1.0385 | 0.0771 | 1.1115 | 0.059* | |
C9 | 0.8530 (7) | −0.03679 (19) | 1.0184 (5) | 0.0482 (12) | |
H9A | 0.7285 | −0.0497 | 1.0010 | 0.058* | |
H9B | 0.9094 | −0.0602 | 1.0766 | 0.058* | |
C10 | 0.4427 (8) | 0.12920 (19) | 0.3459 (5) | 0.0525 (14) | |
C11 | 0.3918 (6) | 0.17775 (18) | 0.2711 (4) | 0.0383 (10) | |
C12 | 0.3151 (7) | 0.1701 (2) | 0.1631 (5) | 0.0526 (13) | |
H12 | 0.2917 | 0.1346 | 0.1368 | 0.063* | |
C13 | 0.2727 (7) | 0.2146 (3) | 0.0936 (4) | 0.0576 (14) | |
H13 | 0.2221 | 0.2087 | 0.0212 | 0.069* | |
C14 | 0.3047 (7) | 0.2672 (2) | 0.1308 (4) | 0.0487 (12) | |
H14 | 0.2751 | 0.2973 | 0.0850 | 0.058* | |
C15 | 0.3824 (6) | 0.27426 (18) | 0.2384 (4) | 0.0374 (9) | |
C16 | 0.4265 (5) | 0.23108 (17) | 0.3089 (4) | 0.0321 (9) | |
H16 | 0.4788 | 0.2374 | 0.3808 | 0.039* | |
C17 | 1.0131 (8) | 0.01112 (19) | 0.6161 (4) | 0.0502 (13) | |
H17A | 1.0734 | −0.0221 | 0.6446 | 0.060* | |
H17B | 0.9935 | 0.0351 | 0.6793 | 0.060* | |
C18 | 0.8675 (7) | −0.03935 (18) | 0.4627 (5) | 0.0497 (12) | |
H18A | 0.7512 | −0.0490 | 0.4238 | 0.060* | |
H18B | 0.9264 | −0.0730 | 0.4897 | 0.060* | |
H1 | 0.489 (9) | 0.0289 (17) | 0.225 (4) | 0.09 (2)* | |
H2 | 0.540 (10) | −0.0251 (13) | 0.222 (4) | 0.09 (3)* | |
H2A | 0.785 (5) | 0.0204 (18) | 1.120 (2) | 0.032 (12)* | |
H4A | 0.767 (7) | −0.022 (2) | 0.605 (4) | 0.067 (18)* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Ag1 | 0.0512 (2) | 0.0434 (2) | 0.0627 (3) | 0.01633 (16) | −0.00099 (18) | 0.00906 (17) |
Ag2 | 0.0541 (3) | 0.0412 (2) | 0.1169 (4) | 0.01428 (18) | 0.0116 (3) | 0.0248 (2) |
O1 | 0.073 (3) | 0.048 (2) | 0.061 (2) | 0.0236 (18) | −0.0126 (19) | 0.0036 (17) |
O2 | 0.129 (4) | 0.035 (2) | 0.098 (3) | 0.008 (2) | −0.032 (3) | −0.016 (2) |
O3 | 0.089 (3) | 0.054 (2) | 0.069 (3) | 0.002 (2) | −0.011 (2) | −0.025 (2) |
O4 | 0.099 (3) | 0.0325 (19) | 0.082 (3) | 0.0035 (19) | 0.029 (2) | 0.0074 (18) |
O5 | 0.078 (3) | 0.043 (2) | 0.063 (2) | 0.0231 (19) | 0.015 (2) | 0.0131 (18) |
O6 | 0.089 (3) | 0.0272 (18) | 0.115 (4) | −0.0083 (18) | 0.052 (3) | −0.001 (2) |
O7 | 0.095 (3) | 0.038 (2) | 0.084 (3) | −0.003 (2) | −0.016 (3) | −0.014 (2) |
O8 | 0.121 (4) | 0.038 (2) | 0.107 (4) | 0.007 (2) | 0.008 (3) | 0.028 (2) |
O9 | 0.084 (3) | 0.050 (2) | 0.080 (3) | −0.001 (2) | 0.036 (2) | −0.005 (2) |
N1 | 0.054 (3) | 0.034 (2) | 0.059 (3) | −0.0019 (18) | 0.019 (2) | −0.0030 (19) |
N2 | 0.0368 (19) | 0.0347 (19) | 0.0353 (19) | 0.0058 (15) | 0.0082 (15) | 0.0027 (15) |
N3 | 0.049 (2) | 0.030 (2) | 0.075 (3) | 0.0021 (17) | 0.010 (2) | 0.006 (2) |
N4 | 0.051 (3) | 0.034 (2) | 0.067 (3) | 0.0024 (18) | 0.019 (2) | 0.0160 (19) |
C1 | 0.047 (3) | 0.037 (3) | 0.068 (3) | 0.005 (2) | −0.004 (2) | −0.001 (2) |
C2 | 0.028 (2) | 0.037 (2) | 0.043 (2) | 0.0018 (17) | −0.0019 (17) | −0.0033 (18) |
C3 | 0.037 (2) | 0.051 (3) | 0.042 (3) | 0.001 (2) | 0.0031 (19) | −0.012 (2) |
C4 | 0.035 (2) | 0.071 (3) | 0.033 (2) | 0.004 (2) | −0.0043 (18) | −0.003 (2) |
C5 | 0.036 (2) | 0.052 (3) | 0.045 (3) | 0.008 (2) | 0.011 (2) | 0.015 (2) |
C6 | 0.031 (2) | 0.037 (2) | 0.038 (2) | −0.0002 (17) | 0.0070 (17) | 0.0003 (18) |
C7 | 0.029 (2) | 0.039 (2) | 0.036 (2) | 0.0006 (17) | −0.0019 (17) | 0.0004 (17) |
C8 | 0.044 (3) | 0.047 (3) | 0.057 (3) | 0.006 (2) | −0.002 (2) | −0.021 (2) |
C9 | 0.039 (3) | 0.032 (2) | 0.075 (4) | −0.0015 (19) | 0.011 (2) | 0.002 (2) |
C10 | 0.058 (3) | 0.031 (2) | 0.073 (4) | 0.008 (2) | 0.039 (3) | 0.004 (2) |
C11 | 0.035 (2) | 0.033 (2) | 0.049 (3) | −0.0038 (18) | 0.0152 (19) | −0.0028 (19) |
C12 | 0.046 (3) | 0.053 (3) | 0.059 (3) | −0.020 (2) | 0.011 (2) | −0.020 (3) |
C13 | 0.042 (3) | 0.091 (4) | 0.039 (3) | −0.010 (3) | −0.002 (2) | −0.010 (3) |
C14 | 0.039 (3) | 0.063 (3) | 0.044 (3) | 0.002 (2) | 0.001 (2) | 0.014 (2) |
C15 | 0.030 (2) | 0.036 (2) | 0.048 (3) | −0.0008 (17) | 0.0065 (18) | 0.0033 (19) |
C16 | 0.029 (2) | 0.031 (2) | 0.036 (2) | −0.0001 (16) | 0.0031 (16) | −0.0015 (16) |
C17 | 0.081 (4) | 0.032 (2) | 0.036 (2) | 0.012 (2) | −0.003 (2) | 0.0019 (19) |
C18 | 0.050 (3) | 0.025 (2) | 0.071 (3) | −0.0030 (19) | −0.018 (2) | 0.002 (2) |
Geometric parameters (Å, º) top
Ag1—O1 | 2.107 (3) | C4—H4 | 0.9300 |
Ag1—N2 | 2.147 (4) | C5—C6 | 1.386 (6) |
Ag2—O5 | 2.132 (3) | C5—H5 | 0.9300 |
Ag2—N4 | 2.174 (4) | C6—C7 | 1.376 (6) |
O1—C1 | 1.259 (6) | C7—H7 | 0.9300 |
O2—C1 | 1.239 (6) | C8—C9i | 1.494 (7) |
O3—N1 | 1.218 (6) | C8—H8A | 0.9700 |
O4—N1 | 1.225 (5) | C8—H8B | 0.9700 |
O5—C10 | 1.267 (7) | C9—C8i | 1.494 (7) |
O6—C10 | 1.240 (6) | C9—H9A | 0.9700 |
O7—N3 | 1.213 (6) | C9—H9B | 0.9700 |
O8—N3 | 1.214 (6) | C10—C11 | 1.513 (7) |
O9—H1 | 0.841 (10) | C11—C12 | 1.387 (7) |
O9—H2 | 0.841 (10) | C11—C16 | 1.391 (6) |
N1—C6 | 1.463 (6) | C12—C13 | 1.388 (8) |
N2—C8 | 1.470 (6) | C12—H12 | 0.9300 |
N2—C9 | 1.480 (6) | C13—C14 | 1.366 (8) |
N2—H2A | 0.895 (10) | C13—H13 | 0.9300 |
N3—C15 | 1.470 (6) | C14—C15 | 1.383 (7) |
N4—C18 | 1.475 (7) | C14—H14 | 0.9300 |
N4—C17 | 1.475 (7) | C15—C16 | 1.371 (6) |
N4—H4A | 0.897 (10) | C16—H16 | 0.9300 |
C1—C2 | 1.510 (6) | C17—C18ii | 1.488 (7) |
C2—C3 | 1.378 (6) | C17—H17A | 0.9700 |
C2—C7 | 1.388 (6) | C17—H17B | 0.9700 |
C3—C4 | 1.383 (7) | C18—C17ii | 1.488 (7) |
C3—H3 | 0.9300 | C18—H18A | 0.9700 |
C4—C5 | 1.367 (7) | C18—H18B | 0.9700 |
| | | |
O1—Ag1—N2 | 165.85 (15) | N2—C8—H8A | 109.6 |
O5—Ag2—N4 | 168.12 (16) | C9i—C8—H8A | 109.6 |
C1—O1—Ag1 | 120.8 (3) | N2—C8—H8B | 109.6 |
C10—O5—Ag2 | 113.6 (3) | C9i—C8—H8B | 109.6 |
H1—O9—H2 | 108 (3) | H8A—C8—H8B | 108.1 |
O3—N1—O4 | 123.6 (5) | N2—C9—C8i | 109.0 (4) |
O3—N1—C6 | 118.7 (4) | N2—C9—H9A | 109.9 |
O4—N1—C6 | 117.6 (4) | C8i—C9—H9A | 109.9 |
C8—N2—C9 | 109.0 (3) | N2—C9—H9B | 109.9 |
C8—N2—Ag1 | 115.4 (3) | C8i—C9—H9B | 109.9 |
C9—N2—Ag1 | 114.1 (3) | H9A—C9—H9B | 108.3 |
C8—N2—H2A | 111 (3) | O6—C10—O5 | 126.0 (5) |
C9—N2—H2A | 106 (3) | O6—C10—C11 | 118.0 (6) |
Ag1—N2—H2A | 101 (3) | O5—C10—C11 | 116.0 (4) |
O7—N3—O8 | 123.0 (5) | C12—C11—C16 | 118.9 (4) |
O7—N3—C15 | 118.8 (4) | C12—C11—C10 | 121.0 (4) |
O8—N3—C15 | 118.2 (5) | C16—C11—C10 | 120.1 (4) |
C18—N4—C17 | 108.7 (4) | C11—C12—C13 | 120.9 (5) |
C18—N4—Ag2 | 112.3 (3) | C11—C12—H12 | 119.5 |
C17—N4—Ag2 | 113.2 (3) | C13—C12—H12 | 119.5 |
C18—N4—H4A | 107 (4) | C14—C13—C12 | 120.5 (5) |
C17—N4—H4A | 110 (4) | C14—C13—H13 | 119.8 |
Ag2—N4—H4A | 105 (4) | C12—C13—H13 | 119.8 |
O2—C1—O1 | 126.5 (5) | C13—C14—C15 | 118.1 (5) |
O2—C1—C2 | 118.0 (5) | C13—C14—H14 | 121.0 |
O1—C1—C2 | 115.5 (4) | C15—C14—H14 | 121.0 |
C3—C2—C7 | 119.3 (4) | C16—C15—C14 | 122.9 (4) |
C3—C2—C1 | 120.9 (4) | C16—C15—N3 | 118.0 (4) |
C7—C2—C1 | 119.8 (4) | C14—C15—N3 | 119.2 (4) |
C2—C3—C4 | 120.6 (4) | C15—C16—C11 | 118.8 (4) |
C2—C3—H3 | 119.7 | C15—C16—H16 | 120.6 |
C4—C3—H3 | 119.7 | C11—C16—H16 | 120.6 |
C5—C4—C3 | 121.1 (4) | N4—C17—C18ii | 110.3 (4) |
C5—C4—H4 | 119.5 | N4—C17—H17A | 109.6 |
C3—C4—H4 | 119.5 | C18ii—C17—H17A | 109.6 |
C4—C5—C6 | 117.7 (4) | N4—C17—H17B | 109.6 |
C4—C5—H5 | 121.1 | C18ii—C17—H17B | 109.6 |
C6—C5—H5 | 121.1 | H17A—C17—H17B | 108.1 |
C7—C6—C5 | 122.5 (4) | N4—C18—C17ii | 110.2 (4) |
C7—C6—N1 | 118.5 (4) | N4—C18—H18A | 109.6 |
C5—C6—N1 | 119.0 (4) | C17ii—C18—H18A | 109.6 |
C6—C7—C2 | 118.8 (4) | N4—C18—H18B | 109.6 |
C6—C7—H7 | 120.6 | C17ii—C18—H18B | 109.6 |
C2—C7—H7 | 120.6 | H18A—C18—H18B | 108.1 |
N2—C8—C9i | 110.3 (4) | | |
| | | |
N2—Ag1—O1—C1 | 173.1 (5) | Ag1—N2—C8—C9i | −69.6 (4) |
N4—Ag2—O5—C10 | 76.8 (10) | C8—N2—C9—C8i | −59.5 (6) |
O1—Ag1—N2—C8 | −58.6 (7) | Ag1—N2—C9—C8i | 71.1 (4) |
O1—Ag1—N2—C9 | 174.0 (6) | Ag2—O5—C10—O6 | 14.7 (7) |
O5—Ag2—N4—C18 | −45.0 (10) | Ag2—O5—C10—C11 | −164.2 (3) |
O5—Ag2—N4—C17 | 78.6 (10) | O6—C10—C11—C12 | −13.2 (7) |
Ag1—O1—C1—O2 | 9.7 (9) | O5—C10—C11—C12 | 165.8 (4) |
Ag1—O1—C1—C2 | −167.9 (3) | O6—C10—C11—C16 | 168.6 (4) |
O2—C1—C2—C3 | 1.7 (8) | O5—C10—C11—C16 | −12.3 (6) |
O1—C1—C2—C3 | 179.5 (5) | C16—C11—C12—C13 | −0.2 (7) |
O2—C1—C2—C7 | −175.9 (5) | C10—C11—C12—C13 | −178.4 (5) |
O1—C1—C2—C7 | 1.9 (7) | C11—C12—C13—C14 | −0.5 (8) |
C7—C2—C3—C4 | 1.2 (7) | C12—C13—C14—C15 | 0.9 (8) |
C1—C2—C3—C4 | −176.5 (4) | C13—C14—C15—C16 | −0.6 (7) |
C2—C3—C4—C5 | 0.3 (7) | C13—C14—C15—N3 | 179.2 (4) |
C3—C4—C5—C6 | −1.0 (7) | O7—N3—C15—C16 | −3.3 (7) |
C4—C5—C6—C7 | 0.4 (7) | O8—N3—C15—C16 | 176.8 (5) |
C4—C5—C6—N1 | 180.0 (4) | O7—N3—C15—C14 | 176.8 (5) |
O3—N1—C6—C7 | 2.5 (6) | O8—N3—C15—C14 | −3.1 (7) |
O4—N1—C6—C7 | −177.4 (4) | C14—C15—C16—C11 | −0.1 (7) |
O3—N1—C6—C5 | −177.1 (5) | N3—C15—C16—C11 | −179.9 (4) |
O4—N1—C6—C5 | 3.0 (6) | C12—C11—C16—C15 | 0.5 (6) |
C5—C6—C7—C2 | 1.1 (6) | C10—C11—C16—C15 | 178.7 (4) |
N1—C6—C7—C2 | −178.5 (4) | C18—N4—C17—C18ii | 59.1 (5) |
C3—C2—C7—C6 | −1.8 (6) | Ag2—N4—C17—C18ii | −66.5 (4) |
C1—C2—C7—C6 | 175.9 (4) | C17—N4—C18—C17ii | −59.1 (5) |
C9—N2—C8—C9i | 60.4 (6) | Ag2—N4—C18—C17ii | 67.1 (4) |
Symmetry codes: (i) −x+2, −y, −z+2; (ii) −x+2, −y, −z+1. |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
N4—H4A···O6iii | 0.90 (1) | 2.09 (2) | 2.968 (5) | 165 (5) |
N2—H2A···O9iv | 0.90 (1) | 2.10 (3) | 2.881 (6) | 146 (4) |
O9—H2···O2iii | 0.84 (1) | 1.86 (2) | 2.688 (6) | 168 (6) |
O9—H1···O6 | 0.84 (1) | 1.91 (1) | 2.745 (6) | 177 (7) |
Symmetry codes: (iii) −x+1, −y, −z+1; (iv) x, y, z+1. |