Acta Cryst. (2005). E61, m772-m774  [ doi:10.1107/S1600536805009062 ]

Diaqua[(1R,2R)-N,N'-bis(3,5-dibromosalicylidene)cyclohexane-1,2-diamine-⁴O,N,N',O']manganese(III) perchlorate dihydrate

T. Akitsu, Y. Takeuchi and Y. Einaga

Abstract: The crystal structure of the title compound, [Mn(C₂₀H₁₆Br₄N₂O₂)(H₂O)₂](ClO₄)·2H₂O, has been determined. The mononuclear complex affords an elongated octahedral MnN₂O₄ coordination geometry with the four donor atoms of the tetradentate chiral Schiff base in the equatorial plane and with two aqua ligands in axial positions with Mn-O = 2.278  (9) and 2.269  (10)  Å.

Online 31 March 2005

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