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Acta Cryst. (2005). E61, o1173-o1175  [ doi:10.1107/S1600536805009281 ]

Methyl [beta]-N-(3-nitrophenylmethylene)dithiocarbazate

Y.-L. Zhang, S. Shan and D.-J. Xu

Abstract: Crystals of the title compound, C9H9N3O2S2, were obtained from a condensation reaction of S-methyl dithiocarbazate and 3-nitrobenzaldehyde. The planar dithiocarbazate moiety subtends an angle of 10.54  (8)° with respect to the plane of the nitrophenyl ring. Electron delocalization occurs between the imino and dithiocarboxyl groups. The partially overlapped arrangement of parallel benzene rings of neighboring molecules, with a face-to-face distance of 3.343  (8)  Å, suggests the existence of [pi]-[pi] stacking.

Online 31 March 2005


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