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Acta Cryst. (2005). E61, o971-o973  [ doi:10.1107/S160053680500721X ]

4,5-Bis(pivaloylsulfanyl)-1,3-dithiolane-2-thione

Y. L. Wang, W. T. Yu, D. Xu, X. Q. Wang and G. H. Zhang

Abstract: The title compound, C13H18O2S5, possesses twofold symmetry and is composed of two pivalyl groups lying on opposite sides of the planar 1,3-dithiole-2-thione conjugated moiety. Owing to the introduction of the C=O electron-acceptor group the adjacent C-S bond length [1.774  (4)  Å] is shorter than that of a typical C-S single bond. In the crystal structure, there are no significant intermolecular hydrogen bonds.

Online 18 March 2005


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