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Acta Cryst. (2005). E61, i49-i51 [ doi:10.1107/S1600536805007579 ]
![[mu]](/logos/entities/mu_rmgif.gif)
-sulfato-1![[kappa]](/logos/entities/kappa_rmgif.gif)
O:2O')bis[cis-dioxido-cis-bis(sulfato-O)tungstate(VI)]Abstract: The title compound, K8[{WVIO2(SO4)2}2(-SO4)2], precipitated from a melt of tungsten trioxide and potassium sulfate in potassium pyrosulfate. The WVI coordination sphere in the independent K4[WVIO2(SO4)3] moiety is completed by inversion symmetry, resulting in a dimer with two bridging sulfate ligands and a unit cell with two dimeric units.
Online 18 March 2005
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