Acta Cryst. (2005). E61, m641-m643  [ doi:10.1107/S1600536805006173 ]

Di--chloro-bis{chloro[3,5-dimethyl-1-(thiocarbamoyl)pyrazole-²N²,S]cadmium(II)}

I. Radosavljevic Evans, K. Mészáros Szécsényi and V. M. Leovac

Abstract: The crystal structure of the title compound, [Cd₂Cl₄(C₆H₉N₃S)₂], has been determined. The compound is isomorphous with the previously reported Cu^II and Co^II complexes. It is centrosymmetric and contains binuclear molecular units with five-coordinate Cd atoms, doubly bridged by Cl atoms. The structure is stabilized by a two-dimensional network of hydrogen bonds involving the terminal Cl atoms as acceptors and thiocarbamoyl group N atoms as donors.

Online 4 March 2005

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