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Acta Cryst. (2005). E61, o1245-o1247  [ doi:10.1107/S1600536805010135 ]

N,N'-Diphenylethylenediamine, an N-H...[pi]- and C-H...[pi]-bonded network

A. Lennartson, T. Kokoli and M. Håkansson

Abstract: N,N'-Diphenylethylenediamine, C14H16N2, forms monoclinic crystals, with a centre of symmetry at the mid-point of the central C-C bond. In the crystal structure, the intermolecular interactions are primarily of N-H...[pi] and C-H...[pi] character, without any contribution from N-H...N hydrogen bonding. The N-H...[pi] and C-H...[pi] interactions, when considered separately, give rise to two sets of layers that, on superposition, generate a network structure.

Online 9 April 2005


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