Acta Cryst. (2005). E61, m989-m991  [ doi:10.1107/S1600536805012584 ]

catena-Poly[[aqua(2,2'-bipyridine-²N,N')manganese(II)]--4-carboxylatophenoxyacetato-³O,O':O'']

S. Gao, L.-H. Huo, J.-W. Liu and H. Zhao

Abstract: In the title coordination polymer, [Mn(4-CPOA)(2,2'-bipy)(H₂O)]_n [where 4-CPOA^2- is 4-carboxylatophenoxyacetate (C₉H₆O₅) and 2,2'-bipy is 2,2'-bipyridine (C₁₀H₈N₂)], each Mn^II ion displays a distorted octahedral coordination configuration, defined by three carboxyl O atoms from two different 4-CPOA^2- groups, two N atoms from the 2,2'-bipyridine ligand and one water molecule. Adjacent Mn^II ions are linked by carboxylate groups into a one-dimensional chain structure with a shortest MnMn distance of 9.771 (3) Å. A two-dimensional supramolecular network is constructed through O-HO intermolecular hydrogen bonds and - stacking interactions.

Online 27 April 2005

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