Acta Cryst. (2005). E61, m830-m831  [ doi:10.1107/S1600536805009633 ]

High-spin [Fe(TTP)(THF)₂]

C.-J. Hu, B. C. Noll and W. R. Scheidt

Abstract: The title compound, bis(tetrahydrofuran)(5,10,15,20-tetra-p-tolylporphyrinato)iron(II), [Fe(C₄₈H₃₆N₄)(C₄H₈O)₂] or [Fe(TTP)(THF)₂] (TTP = dianion of meso-tetratolylporphyrin), is a six-coordinate high-spin iron(II) tetratolylporphyrin with two tetrahydrofuran molecules as axial ligands. The Fe^II atom is at an inversion center. The average Fe-N distance is 2.067 (7) Å and the Fe-O distance is 2.3208 (8) Å.

Online 9 April 2005

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