Acta Cryst. (2005). E61, m1138-m1139  [ doi:10.1107/S1600536805012869 ]

Tetraethylammonium bis(benzene-1,2-dithiolato)(2-disulfanylbenzenethiolato)niobate

P. A. Petrov, N. V. Kuratieva, D. Y. Naumov and S. N. Konchenko

Abstract: The title compound, (C₈H₂₀N)[Nb(C₆H₄S₂)₂(C₆H₄S₃)], is the major product of the reaction of (Et₄N)₄[Nb₂S₄(NCS)₈] and disodium benzene-1,2-dithiolate. The coordination environment of the Nb atom contains seven S atoms, viz. four S atoms from two benzene-1,2-dithiolate ligands and three S atoms from 2-disulfanylbenzenethiolate. The Nb-S distances are in the range 2.4391 (6)-2.5932 (7) Å.

Online 21 May 2005

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