Acta Cryst. (2005). E61, m1138-m1139 [ doi:10.1107/S1600536805012869 ]
Abstract: The title compound, (C8H20N)[Nb(C6H4S2)2(C6H4S3)], is the major product of the reaction of (Et4N)4[Nb2S4(NCS)8] and disodium benzene-1,2-dithiolate. The coordination environment of the Nb atom contains seven S atoms, viz. four S atoms from two benzene-1,2-dithiolate ligands and three S atoms from 2-disulfanylbenzenethiolate. The Nb-S distances are in the range 2.4391 (6)-2.5932 (7) Å.
Online 21 May 2005
Copyright © International Union of Crystallography