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Acta Cryst. (2005). E61, m1009-m1011  [ doi:10.1107/S160053680500591X ]

Bis([mu]-2,6-diformyl-4-methylphenolato)bis[bis(2,6-diformyl-4-methylphenolato)neodymium(III)]

M. A. Singh-Wilmot, I. A. Kahwa and A. J. Lough

Abstract: The title compound, [Nd2(C9H7O3)6], crystallizes from an anhydrous alcoholic mixture of neodymium perchlorate, 2,6-diformyl-4-methylphenol and sodium hydroxide. The structure consists of discrete dinuclear molecules with NdIII ions in eightfold coordination environments. The complete molecule is generated from the asymmetric unit by a crystallographic center of symmetry. Intramolecular and intermolecular [pi]-[pi] stacking and C-H...O interactions help to stabilize the crystal packing.

Online 7 May 2005


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