Acta Cryst. (2005). E61, m1172-m1173  [ doi:10.1107/S1600536805015308 ]

Carbonyl(⁵-cyclopentadienyl)(trimethylsilyl isocyanide)(triphenylphosphine)iron(II) trifluoromethanesulfonate dichloromethane hemisolvate

H. Nakazawa, M. Itazaki and M. Owaribe

Abstract: In the title compound, [Fe(C₅H₅)(C₄H₉NSi)(C₁₈H₁₅P)(CO)](CF₃SO₃)·0.5CH₂Cl₂, the Fe^II atom is coordinated by carbonyl, triphenylphosphine, trimethylsilyl isocyanide and cyclopentadienyl ligands in a typical piano-stool structure. The Fe-C-N-Si arrangement is almost linear and the Fe-C, C-N and N-Si bond distances are 1.836 (3), 1.162 (4) and 1.792 (3) Å, respectively.

Online 21 May 2005

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