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Acta Cryst. (2005). E61, m1166-m1168  [ doi:10.1107/S1600536805015369 ]

Carbonyl([eta]5-cyclopentadienyl)(isocyanotriphenylborato-[kappa]C)(triphenylphosphine-[kappa]P)iron(II)

H. Nakazawa, M. Itazaki and M. Owaribe

Abstract: In the title compound, [Fe(C5H5)(C19H15BN)(C18H15P)(CO)], the FeII atom is coordinated by a carbonyl group, a triphenylphosphine ligand, an isocyanotriphenylborate ligand and a cyclopentadienyl ligand in a piano-stool structure. Two crystallographically independent molecules exist in the asymmetric unit; the Fe-CN, C[triple bond]N and CN-B bond distances are 1.866 (3), 1.157 (3) and 1.584 (4) Å, respectively, for one molecule, and 1.879 (3), 1.157 (3) and 1.587 (4) Å, respectively, for the other.

Online 21 May 2005


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