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Acta Cryst. (2005). E61, o1595-o1597 [ doi:10.1107/S1600536805013309 ]
Abstract: In the crystal structure of the title compound, N-benzyl-N-methylprop-2-yn-1-aminium chloride, C11H14N+·Cl-, the asymmetric unit contains two independent enantiomeric cations related by a pseudo-center of symmetry. In both cations, the protonation occurs at the N atom, and the side chains are roughly perpendicular to the benzene rings. In addition to the conventional N-H
Cl hydrogen bonds, there are several weak hydrogen bonds of the type C-H
Cl. The cations are arranged head-to-head and tail-to-tail, producing hydrophilic and hydrophobic areas
Online 7 May 2005
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