A second polymorph of cyclo-tetra­kis­{μ₂-[(dimethyl­amino)meth­yl]phen­yl-κ³C²:C²,N}copper tetra­hydro­furan solvate

The structure of the title compound, [Cu₄(C₉H₁₂N)₄]·C₄H₈O, has previously been reported in the monoclinic space group C2/c. We report here the structure of a second polymorph which crystallizes in the orthorhombic space group P2₁2₁2₁. The copper complex is located at a general position but exhibits local S₄ symmetry.

Key indicators

• Single-crystal X-ray study
• T = 100 K
• Mean [sigma](C-C) = 0.003 Å
• Disorder in solvent or counterion
• R factor = 0.019
• wR factor = 0.045
• Data-to-parameter ratio = 18.2

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT027_ALERT_3_A _diffrn_reflns_theta_full (too) Low ............       0.00 Deg.
PLAT029_ALERT_3_A _diffrn_measured_fraction_theta_full Low .......       0.00
PLAT037_ALERT_1_A _diffrn_reflns_theta_full .......... Not Given .          ?
PLAT038_ALERT_1_A _diffrn_measured_fraction_theta_max  Not Given .          ?
PLAT039_ALERT_1_A _diffrn_measured_fraction_theta_full Not Given .          ?

Alert level C
PLAT243_ALERT_4_C High  'Solvent' Ueq as Compared to Neighbors for        C3A
PLAT302_ALERT_4_C Anion/Solvent Disorder .........................      50.00 Perc.

Alert level G
REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is
            correct. If it is not, please give the correct count in the
            _publ_section_exptl_refinement section of the submitted CIF.
           From the CIF: _diffrn_reflns_theta_max           27.47
           From the CIF: _reflns_number_total               9022
           Count of symmetry unique reflns         5066
           Completeness (_total/calc)            178.09%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured      3956
           Fraction of Friedel pairs measured     0.781
           Are heavy atom types Z>Si present        yes

   5 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   2 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   0 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   3 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: COLLECT (Nonius, 1998); cell refinement: DENZO (Otwinowski & Minor, 1997); data reduction: DENZO; program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: PLATON (Spek, 2003); software used to prepare material for publication: PLATON.

cyclo-tetrakis{µ₂-[(dimethylamino)methyl]phenyl-κ³C²:C²,N}copper tetrahydrofuran solvate

Crystal data

[Cu4(C9H12N)4]·C4H8O	F(000) = 1792
Mr = 863.05	Dx = 1.450 Mg m^−3
Orthorhombic, P212121	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2ac 2ab	Cell parameters from 64686 reflections
a = 9.4952 (2) Å	θ = 1.3–27.5°
b = 13.2026 (3) Å	µ = 2.16 mm^−1
c = 31.5269 (6) Å	T = 100 K
V = 3952.25 (14) Å^3	Plate, pale yellow
Z = 4	0.42 × 0.24 × 0.15 mm

Data collection

Bruker Nonius KappaCCD area-detector diffractometer	9022 independent reflections
Radiation source: rotating anode	8758 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.047
ω and φ scans	θmax = 27.5°, θmin = 1.3°
Absorption correction: multi-scan (MULABS; Blessing, 1995)	h = −12→12
Tmin = 0.59, Tmax = 0.72	k = −17→17
53905 measured reflections	l = −40→40

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.019	H-atom parameters constrained
wR(F^2) = 0.045	w = 1/[σ^2(Fo^2) + (0.0157P)^2 + 1.2769P] where P = (Fo^2 + 2Fc^2)/3
S = 1.04	(Δ/σ)max = 0.001
9022 reflections	Δρmax = 0.32 e Å^−3
496 parameters	Δρmin = −0.26 e Å^−3
10 restraints	Absolute structure: Flack (1983), with how many Friedel pairs
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: −0.013 (6)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Cu1	0.28994 (2)	0.587106 (15)	0.107245 (6)	0.01566 (5)
Cu2	0.40458 (2)	0.525604 (15)	0.169425 (6)	0.01602 (5)
Cu3	0.39195 (2)	0.376070 (15)	0.125651 (6)	0.01588 (5)
Cu4	0.42917 (2)	0.477468 (16)	0.064348 (6)	0.01647 (5)
N1	0.11604 (16)	0.67766 (11)	0.13174 (4)	0.0196 (3)
C11	0.42577 (19)	0.66803 (13)	0.15006 (5)	0.0171 (3)
C12	0.3348 (2)	0.75135 (13)	0.15761 (5)	0.0183 (4)
C13	0.3791 (2)	0.85166 (13)	0.15204 (6)	0.0229 (4)
H13	0.3148	0.9056	0.1569	0.027*
C14	0.5163 (2)	0.87302 (15)	0.13945 (6)	0.0253 (4)
H14	0.5465	0.9412	0.1361	0.030*
C15	0.6084 (2)	0.79387 (13)	0.13185 (5)	0.0218 (4)
H15	0.7024	0.8075	0.1233	0.026*
C16	0.5630 (2)	0.69347 (13)	0.13675 (5)	0.0194 (4)
H16	0.6275	0.6403	0.1308	0.023*
C17	0.1829 (2)	0.72889 (14)	0.16844 (6)	0.0208 (4)
H17A	0.1782	0.6847	0.1938	0.025*
H17B	0.1324	0.7927	0.1749	0.025*
C18	−0.0125 (2)	0.62431 (16)	0.14439 (6)	0.0271 (4)
H18A	−0.0831	0.6736	0.1538	0.041*
H18B	0.0089	0.5776	0.1677	0.041*
H18C	−0.0494	0.5861	0.1202	0.041*
C19	0.0817 (2)	0.75141 (15)	0.09822 (6)	0.0276 (4)
H19A	0.0122	0.7999	0.1090	0.041*
H19B	0.0427	0.7157	0.0736	0.041*
H19C	0.1673	0.7876	0.0898	0.041*
N2	0.55593 (17)	0.48499 (12)	0.21869 (5)	0.0228 (3)
C21	0.3064 (2)	0.38765 (13)	0.18354 (5)	0.0187 (4)
C22	0.3756 (2)	0.35395 (13)	0.22075 (6)	0.0222 (4)
C23	0.3022 (3)	0.30931 (15)	0.25429 (6)	0.0325 (5)
H23	0.3516	0.2873	0.2788	0.039*
C24	0.1572 (3)	0.29690 (16)	0.25195 (7)	0.0392 (6)
H24	0.1079	0.2651	0.2745	0.047*
C25	0.0847 (3)	0.33089 (15)	0.21664 (7)	0.0330 (5)
H25	−0.0147	0.3234	0.2151	0.040*
C26	0.1582 (2)	0.37614 (14)	0.18335 (6)	0.0231 (4)
H26	0.1066	0.4002	0.1596	0.028*
C27	0.5308 (2)	0.37440 (15)	0.22396 (6)	0.0263 (4)
H27A	0.5662	0.3518	0.2519	0.032*
H27B	0.5816	0.3364	0.2017	0.032*
C28	0.5147 (2)	0.54013 (15)	0.25737 (6)	0.0290 (4)
H28A	0.5771	0.5207	0.2808	0.044*
H28B	0.4172	0.5232	0.2647	0.044*
H28C	0.5225	0.6132	0.2524	0.044*
C29	0.7044 (2)	0.50520 (18)	0.20930 (7)	0.0345 (5)
H29A	0.7189	0.5784	0.2064	0.052*
H29B	0.7305	0.4714	0.1827	0.052*
H29C	0.7632	0.4793	0.2324	0.052*
N3	0.32555 (16)	0.23014 (11)	0.09918 (5)	0.0190 (3)
C31	0.55948 (19)	0.36642 (13)	0.08094 (5)	0.0173 (3)
C32	0.54890 (19)	0.26678 (13)	0.06458 (6)	0.0194 (3)
C33	0.6664 (2)	0.20613 (15)	0.05785 (7)	0.0294 (4)
H33	0.6553	0.1406	0.0458	0.035*
C34	0.7996 (2)	0.24052 (15)	0.06858 (8)	0.0327 (5)
H34	0.8801	0.1997	0.0634	0.039*
C35	0.8140 (2)	0.33536 (15)	0.08704 (7)	0.0275 (4)
H35	0.9042	0.3583	0.0958	0.033*
C36	0.69692 (19)	0.39658 (13)	0.09266 (6)	0.0211 (4)
H36	0.7096	0.4617	0.1049	0.025*
C37	0.4016 (2)	0.22542 (13)	0.05824 (6)	0.0212 (4)
H37A	0.3513	0.2661	0.0366	0.025*
H37B	0.4064	0.1545	0.0482	0.025*
C38	0.1735 (2)	0.21558 (15)	0.09272 (7)	0.0262 (4)
H38A	0.1393	0.2645	0.0717	0.039*
H38B	0.1240	0.2259	0.1196	0.039*
H38C	0.1560	0.1466	0.0825	0.039*
C39	0.3772 (2)	0.15172 (14)	0.12860 (7)	0.0304 (4)
H39A	0.3590	0.0845	0.1166	0.046*
H39B	0.3283	0.1581	0.1558	0.046*
H39C	0.4787	0.1604	0.1329	0.046*
N4	0.52110 (18)	0.57058 (12)	0.01466 (5)	0.0232 (3)
C41	0.23877 (19)	0.54481 (13)	0.04798 (5)	0.0177 (3)
C42	0.2684 (2)	0.60157 (13)	0.01087 (5)	0.0211 (4)
C43	0.1723 (2)	0.60661 (15)	−0.02269 (6)	0.0290 (5)
H43	0.1956	0.6444	−0.0474	0.035*
C44	0.0436 (2)	0.55723 (16)	−0.02046 (6)	0.0307 (5)
H44	−0.0228	0.5636	−0.0428	0.037*
C45	0.0128 (2)	0.49849 (15)	0.01478 (6)	0.0261 (4)
H45	−0.0736	0.4624	0.0163	0.031*
C46	0.1089 (2)	0.49271 (13)	0.04783 (5)	0.0202 (3)
H46	0.0862	0.4516	0.0716	0.024*
C47	0.4116 (2)	0.64934 (13)	0.00797 (6)	0.0236 (4)
H47A	0.4240	0.6809	−0.0203	0.028*
H47B	0.4209	0.7029	0.0298	0.028*
C48	0.5338 (3)	0.50398 (15)	−0.02261 (6)	0.0334 (5)
H48A	0.5678	0.5434	−0.0469	0.050*
H48B	0.4415	0.4749	−0.0293	0.050*
H48C	0.6005	0.4493	−0.0164	0.050*
C49	0.6581 (2)	0.61647 (16)	0.02410 (7)	0.0310 (4)
H49A	0.7276	0.5630	0.0292	0.046*
H49B	0.6500	0.6592	0.0494	0.046*
H49C	0.6884	0.6579	0.0000	0.046*
O1	1.0117 (3)	0.0009 (2)	0.15323 (8)	0.0667 (10)	0.731 (4)
C1	0.8718 (6)	0.0209 (4)	0.14329 (15)	0.0596 (13)	0.731 (4)
H1A	0.8136	−0.0406	0.1472	0.072*	0.731 (4)
H1B	0.8632	0.0435	0.1135	0.072*	0.731 (4)
C2	0.8251 (6)	0.1028 (5)	0.17286 (17)	0.0575 (15)	0.731 (4)
H2A	0.7219	0.1013	0.1773	0.069*	0.731 (4)
H2B	0.8531	0.1706	0.1624	0.069*	0.731 (4)
C3	0.9044 (6)	0.0746 (4)	0.21313 (12)	0.0439 (12)	0.731 (4)
H3A	0.9251	0.1350	0.2306	0.053*	0.731 (4)
H3B	0.8510	0.0250	0.2303	0.053*	0.731 (4)
C4	1.0382 (5)	0.0282 (5)	0.19534 (16)	0.0443 (11)	0.731 (4)
H4A	1.1163	0.0778	0.1967	0.053*	0.731 (4)
H4B	1.0651	−0.0322	0.2121	0.053*	0.731 (4)
O1A	0.8268 (6)	0.1512 (4)	0.21913 (17)	0.0357 (17)	0.269 (4)
C1A	0.9193 (12)	0.0746 (7)	0.2306 (2)	0.042 (3)	0.269 (4)
H1C	0.8681	0.0192	0.2452	0.050*	0.269 (4)
H1D	0.9925	0.1011	0.2500	0.050*	0.269 (4)
C2A	0.9850 (12)	0.0365 (11)	0.1906 (4)	0.056 (5)	0.269 (4)
H2C	1.0148	−0.0351	0.1933	0.068*	0.269 (4)
H2D	1.0669	0.0783	0.1822	0.068*	0.269 (4)
C3A	0.8636 (15)	0.0479 (10)	0.1594 (3)	0.071 (5)	0.269 (4)
H3C	0.8980	0.0581	0.1301	0.085*	0.269 (4)
H3D	0.8003	−0.0117	0.1601	0.085*	0.269 (4)
C4A	0.7907 (12)	0.1419 (9)	0.1763 (3)	0.055 (4)	0.269 (4)
H4C	0.8221	0.2025	0.1604	0.066*	0.269 (4)
H4D	0.6874	0.1354	0.1732	0.066*	0.269 (4)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cu1	0.01595 (10)	0.01791 (10)	0.01310 (9)	0.00185 (8)	−0.00055 (8)	−0.00092 (8)
Cu2	0.01798 (10)	0.01477 (9)	0.01531 (9)	−0.00092 (9)	−0.00183 (8)	0.00183 (7)
Cu3	0.01694 (10)	0.01605 (9)	0.01464 (9)	−0.00137 (8)	0.00076 (8)	0.00059 (8)
Cu4	0.01718 (10)	0.01531 (9)	0.01694 (9)	0.00234 (8)	0.00292 (8)	0.00220 (8)
N1	0.0177 (7)	0.0219 (7)	0.0192 (7)	0.0025 (6)	−0.0006 (6)	0.0005 (6)
C11	0.0207 (9)	0.0167 (8)	0.0140 (7)	−0.0009 (7)	−0.0027 (7)	−0.0010 (6)
C12	0.0222 (9)	0.0187 (8)	0.0139 (8)	−0.0008 (7)	0.0007 (7)	−0.0008 (6)
C13	0.0307 (10)	0.0172 (8)	0.0208 (8)	0.0032 (8)	−0.0005 (8)	−0.0024 (6)
C14	0.0344 (11)	0.0172 (8)	0.0243 (9)	−0.0051 (8)	−0.0037 (8)	0.0008 (7)
C15	0.0232 (9)	0.0243 (9)	0.0180 (8)	−0.0053 (8)	−0.0002 (8)	0.0013 (7)
C16	0.0220 (9)	0.0200 (8)	0.0163 (8)	0.0006 (7)	−0.0023 (7)	−0.0014 (6)
C17	0.0236 (10)	0.0220 (9)	0.0168 (8)	0.0024 (7)	0.0037 (7)	−0.0022 (7)
C18	0.0169 (9)	0.0328 (10)	0.0316 (10)	0.0002 (8)	0.0047 (8)	−0.0047 (8)
C19	0.0275 (11)	0.0286 (10)	0.0267 (9)	0.0111 (8)	−0.0036 (8)	0.0035 (7)
N2	0.0243 (8)	0.0241 (8)	0.0202 (7)	−0.0003 (7)	−0.0060 (6)	−0.0001 (6)
C21	0.0243 (9)	0.0141 (8)	0.0177 (8)	−0.0010 (7)	0.0023 (7)	0.0018 (6)
C22	0.0362 (11)	0.0132 (8)	0.0173 (8)	0.0006 (7)	−0.0009 (8)	−0.0001 (6)
C23	0.0616 (15)	0.0192 (9)	0.0167 (9)	−0.0040 (10)	0.0030 (9)	0.0046 (7)
C24	0.0629 (17)	0.0256 (10)	0.0289 (11)	−0.0103 (11)	0.0218 (11)	0.0017 (8)
C25	0.0340 (12)	0.0255 (10)	0.0396 (11)	−0.0075 (9)	0.0170 (10)	−0.0052 (8)
C26	0.0268 (10)	0.0183 (8)	0.0243 (9)	−0.0026 (8)	0.0055 (7)	−0.0013 (7)
C27	0.0337 (11)	0.0220 (9)	0.0232 (9)	0.0059 (8)	−0.0108 (8)	0.0009 (7)
C28	0.0401 (12)	0.0258 (10)	0.0212 (9)	−0.0034 (9)	−0.0066 (8)	−0.0019 (7)
C29	0.0248 (10)	0.0439 (13)	0.0347 (10)	−0.0001 (10)	−0.0101 (9)	0.0002 (9)
N3	0.0143 (7)	0.0168 (7)	0.0258 (8)	−0.0016 (6)	−0.0010 (6)	0.0005 (6)
C31	0.0172 (8)	0.0167 (8)	0.0179 (8)	0.0013 (7)	0.0034 (6)	0.0015 (6)
C32	0.0169 (9)	0.0182 (8)	0.0229 (8)	0.0002 (7)	0.0019 (7)	−0.0016 (7)
C33	0.0234 (10)	0.0192 (9)	0.0455 (12)	0.0029 (8)	0.0039 (9)	−0.0055 (8)
C34	0.0168 (10)	0.0247 (10)	0.0567 (14)	0.0047 (8)	0.0049 (10)	−0.0023 (9)
C35	0.0154 (9)	0.0260 (10)	0.0410 (11)	−0.0024 (8)	−0.0021 (8)	0.0053 (8)
C36	0.0202 (9)	0.0181 (9)	0.0250 (9)	−0.0017 (7)	0.0026 (7)	0.0008 (7)
C37	0.0177 (9)	0.0198 (8)	0.0260 (9)	0.0008 (7)	−0.0002 (8)	−0.0074 (7)
C38	0.0167 (9)	0.0243 (9)	0.0377 (11)	−0.0047 (7)	−0.0013 (8)	−0.0071 (8)
C39	0.0275 (11)	0.0204 (9)	0.0434 (12)	−0.0013 (8)	−0.0054 (9)	0.0113 (8)
N4	0.0279 (9)	0.0177 (8)	0.0240 (8)	0.0014 (7)	0.0098 (7)	0.0022 (6)
C41	0.0225 (9)	0.0169 (8)	0.0136 (7)	0.0026 (7)	0.0005 (6)	−0.0010 (6)
C42	0.0319 (10)	0.0157 (8)	0.0159 (8)	0.0041 (7)	0.0005 (7)	−0.0004 (6)
C43	0.0463 (13)	0.0237 (10)	0.0171 (8)	0.0085 (9)	−0.0037 (8)	0.0027 (7)
C44	0.0353 (12)	0.0321 (11)	0.0246 (9)	0.0115 (9)	−0.0140 (9)	−0.0062 (8)
C45	0.0220 (9)	0.0278 (10)	0.0286 (9)	0.0044 (8)	−0.0056 (8)	−0.0093 (8)
C46	0.0197 (9)	0.0223 (8)	0.0185 (7)	0.0035 (7)	−0.0003 (7)	−0.0020 (6)
C47	0.0327 (11)	0.0163 (8)	0.0217 (8)	0.0018 (8)	0.0054 (8)	0.0057 (6)
C48	0.0481 (13)	0.0248 (10)	0.0273 (10)	0.0008 (9)	0.0159 (9)	−0.0012 (8)
C49	0.0267 (10)	0.0289 (10)	0.0373 (11)	−0.0032 (8)	0.0120 (9)	0.0047 (9)
O1	0.074 (2)	0.082 (2)	0.0442 (15)	0.0323 (17)	−0.0009 (13)	−0.0143 (14)
C1	0.064 (3)	0.059 (3)	0.056 (3)	−0.018 (2)	−0.023 (2)	−0.006 (2)
C2	0.036 (3)	0.075 (4)	0.061 (3)	0.019 (2)	0.010 (2)	0.023 (3)
C3	0.061 (3)	0.0336 (19)	0.037 (2)	−0.0060 (19)	0.016 (2)	−0.0011 (19)
C4	0.036 (3)	0.052 (3)	0.045 (2)	−0.002 (2)	−0.0030 (19)	0.0038 (19)
O1A	0.037 (3)	0.030 (3)	0.040 (3)	0.003 (2)	0.001 (3)	0.003 (2)
C1A	0.054 (7)	0.029 (5)	0.042 (7)	0.005 (5)	0.005 (6)	−0.005 (6)
C2A	0.050 (10)	0.055 (7)	0.064 (9)	0.013 (8)	0.013 (8)	0.021 (6)
C3A	0.115 (14)	0.057 (9)	0.042 (8)	0.026 (9)	−0.031 (8)	−0.012 (6)
C4A	0.028 (7)	0.086 (12)	0.051 (7)	0.001 (7)	−0.010 (5)	0.006 (7)

Geometric parameters (Å, º)

Cu1—C41	2.0096 (17)	C32—C33	1.390 (3)
Cu1—C11	2.1510 (17)	C32—C37	1.514 (3)
Cu1—N1	2.1800 (15)	C33—C34	1.386 (3)
Cu1—Cu4	2.3816 (3)	C33—H33	0.9500
Cu1—Cu2	2.3848 (3)	C34—C35	1.388 (3)
Cu1—Cu3	3.0063 (3)	C34—H34	0.9500
Cu2—C11	1.9872 (17)	C35—C36	1.386 (3)
Cu2—C21	2.0938 (17)	C35—H35	0.9500
Cu2—N2	2.1830 (15)	C36—H36	0.9500
Cu2—Cu3	2.4117 (3)	C37—H37A	0.9900
Cu3—C21	2.0033 (17)	C37—H37B	0.9900
Cu3—C31	2.1292 (17)	C38—H38A	0.9800
Cu3—N3	2.1922 (15)	C38—H38B	0.9800
Cu3—Cu4	2.3775 (3)	C38—H38C	0.9800
Cu4—C31	1.9885 (17)	C39—H39A	0.9800
Cu4—C41	2.0796 (18)	C39—H39B	0.9800
Cu4—N4	2.1741 (15)	C39—H39C	0.9800
N1—C18	1.465 (2)	N4—C49	1.466 (3)
N1—C19	1.473 (2)	N4—C48	1.473 (2)
N1—C17	1.483 (2)	N4—C47	1.486 (2)
C11—C16	1.410 (3)	C41—C46	1.412 (3)
C11—C12	1.419 (2)	C41—C42	1.417 (2)
C12—C13	1.401 (3)	C42—C43	1.399 (3)
C12—C17	1.512 (3)	C42—C47	1.502 (3)
C13—C14	1.391 (3)	C43—C44	1.387 (3)
C13—H13	0.9500	C43—H43	0.9500
C14—C15	1.383 (3)	C44—C45	1.386 (3)
C14—H14	0.9500	C44—H44	0.9500
C15—C16	1.402 (2)	C45—C46	1.387 (3)
C15—H15	0.9500	C45—H45	0.9500
C16—H16	0.9500	C46—H46	0.9500
C17—H17A	0.9900	C47—H47A	0.9900
C17—H17B	0.9900	C47—H47B	0.9900
C18—H18A	0.9800	C48—H48A	0.9800
C18—H18B	0.9800	C48—H48B	0.9800
C18—H18C	0.9800	C48—H48C	0.9800
C19—H19A	0.9800	C49—H49A	0.9800
C19—H19B	0.9800	C49—H49B	0.9800
C19—H19C	0.9800	C49—H49C	0.9800
N2—C29	1.465 (3)	O1—C1	1.390 (6)
N2—C28	1.473 (2)	O1—C4	1.398 (5)
N2—C27	1.489 (2)	C1—C2	1.495 (7)
C21—C26	1.416 (3)	C1—H1A	0.9900
C21—C22	1.416 (2)	C1—H1B	0.9900
C22—C23	1.397 (3)	C2—C3	1.523 (6)
C22—C27	1.501 (3)	C2—H2A	0.9900
C23—C24	1.388 (4)	C2—H2B	0.9900
C23—H23	0.9500	C3—C4	1.517 (6)
C24—C25	1.384 (3)	C3—H3A	0.9900
C24—H24	0.9500	C3—H3B	0.9900
C25—C26	1.394 (3)	C4—H4A	0.9900
C25—H25	0.9500	C4—H4B	0.9900
C26—H26	0.9500	O1A—C1A	1.389 (6)
C27—H27A	0.9900	O1A—C4A	1.398 (5)
C27—H27B	0.9900	C1A—C2A	1.494 (7)
C28—H28A	0.9800	C1A—H1C	0.9900
C28—H28B	0.9800	C1A—H1D	0.9900
C28—H28C	0.9800	C2A—C3A	1.523 (6)
C29—H29A	0.9800	C2A—H2C	0.9900
C29—H29B	0.9800	C2A—H2D	0.9900
C29—H29C	0.9800	C3A—C4A	1.518 (6)
N3—C38	1.470 (2)	C3A—H3C	0.9900
N3—C39	1.474 (2)	C3A—H3D	0.9900
N3—C37	1.480 (2)	C4A—H4C	0.9900
C31—C36	1.413 (3)	C4A—H4D	0.9900
C31—C32	1.417 (2)
C41—Cu1—C11	150.04 (7)	C38—N3—C39	108.78 (15)
C41—Cu1—N1	107.38 (6)	C38—N3—C37	110.66 (14)
C11—Cu1—N1	87.68 (6)	C39—N3—C37	110.89 (15)
C41—Cu1—Cu4	55.76 (5)	C38—N3—Cu3	116.74 (11)
C11—Cu1—Cu4	108.99 (5)	C39—N3—Cu3	106.39 (11)
N1—Cu1—Cu4	162.74 (4)	C37—N3—Cu3	103.21 (10)
C41—Cu1—Cu2	141.26 (5)	C36—C31—C32	114.97 (16)
C11—Cu1—Cu2	51.65 (4)	C36—C31—Cu4	115.83 (12)
N1—Cu1—Cu2	103.96 (4)	C32—C31—Cu4	123.00 (13)
Cu4—Cu1—Cu2	90.372 (10)	C36—C31—Cu3	119.99 (12)
C41—Cu1—Cu3	89.99 (5)	C32—C31—Cu3	104.10 (12)
C11—Cu1—Cu3	98.40 (5)	Cu4—C31—Cu3	70.44 (6)
N1—Cu1—Cu3	133.15 (4)	C33—C32—C31	122.27 (17)
Cu4—Cu1—Cu3	50.763 (7)	C33—C32—C37	120.89 (16)
Cu2—Cu1—Cu3	51.589 (7)	C31—C32—C37	116.64 (15)
C11—Cu2—C21	158.98 (7)	C34—C33—C32	120.44 (18)
C11—Cu2—N2	112.61 (7)	C34—C33—H33	119.8
C21—Cu2—N2	85.88 (6)	C32—C33—H33	119.8
C11—Cu2—Cu1	58.09 (5)	C33—C34—C35	119.22 (18)
C21—Cu2—Cu1	105.53 (5)	C33—C34—H34	120.4
N2—Cu2—Cu1	165.70 (4)	C35—C34—H34	120.4
C11—Cu2—Cu3	127.14 (5)	C36—C35—C34	120.04 (18)
C21—Cu2—Cu3	52.22 (5)	C36—C35—H35	120.0
N2—Cu2—Cu3	103.82 (4)	C34—C35—H35	120.0
Cu1—Cu2—Cu3	77.622 (9)	C35—C36—C31	122.89 (16)
C21—Cu3—C31	155.57 (7)	C35—C36—H36	118.6
C21—Cu3—N3	107.29 (6)	C31—C36—H36	118.6
C31—Cu3—N3	84.85 (6)	N3—C37—C32	108.69 (14)
C21—Cu3—Cu4	139.27 (5)	N3—C37—H37A	110.0
C31—Cu3—Cu4	52.01 (5)	C32—C37—H37A	110.0
N3—Cu3—Cu4	103.19 (4)	N3—C37—H37B	110.0
C21—Cu3—Cu2	55.70 (5)	C32—C37—H37B	110.0
C31—Cu3—Cu2	112.99 (5)	H37A—C37—H37B	108.3
N3—Cu3—Cu2	162.09 (4)	N3—C38—H38A	109.5
Cu4—Cu3—Cu2	89.820 (10)	N3—C38—H38B	109.5
C21—Cu3—Cu1	88.54 (5)	H38A—C38—H38B	109.5
C31—Cu3—Cu1	99.69 (5)	N3—C38—H38C	109.5
N3—Cu3—Cu1	130.42 (4)	H38A—C38—H38C	109.5
Cu4—Cu3—Cu1	50.885 (7)	H38B—C38—H38C	109.5
Cu2—Cu3—Cu1	50.789 (7)	N3—C39—H39A	109.5
C31—Cu4—C41	157.13 (7)	N3—C39—H39B	109.5
C31—Cu4—N4	110.89 (7)	H39A—C39—H39B	109.5
C41—Cu4—N4	85.90 (7)	N3—C39—H39C	109.5
C31—Cu4—Cu3	57.55 (5)	H39A—C39—H39C	109.5
C41—Cu4—Cu3	108.25 (5)	H39B—C39—H39C	109.5
N4—Cu4—Cu3	164.53 (5)	C49—N4—C48	109.64 (16)
C31—Cu4—Cu1	130.10 (5)	C49—N4—C47	111.15 (15)
C41—Cu4—Cu1	53.02 (5)	C48—N4—C47	111.21 (16)
N4—Cu4—Cu1	106.76 (4)	C49—N4—Cu4	116.35 (12)
Cu3—Cu4—Cu1	78.352 (9)	C48—N4—Cu4	105.68 (11)
C18—N1—C19	109.18 (16)	C47—N4—Cu4	102.54 (10)
C18—N1—C17	111.33 (14)	C46—C41—C42	115.34 (16)
C19—N1—C17	110.66 (15)	C46—C41—Cu1	110.47 (12)
C18—N1—Cu1	117.65 (12)	C42—C41—Cu1	124.92 (13)
C19—N1—Cu1	106.02 (11)	C46—C41—Cu4	123.48 (12)
C17—N1—Cu1	101.68 (11)	C42—C41—Cu4	104.97 (13)
C16—C11—C12	115.34 (16)	Cu1—C41—Cu4	71.21 (6)
C16—C11—Cu2	114.24 (13)	C43—C42—C41	121.35 (18)
C12—C11—Cu2	128.35 (13)	C43—C42—C47	121.63 (16)
C16—C11—Cu1	119.07 (12)	C41—C42—C47	116.87 (16)
C12—C11—Cu1	97.20 (12)	C44—C43—C42	120.93 (18)
Cu2—C11—Cu1	70.25 (5)	C44—C43—H43	119.5
C13—C12—C11	121.96 (17)	C42—C43—H43	119.5
C13—C12—C17	120.03 (17)	C45—C44—C43	119.28 (18)
C11—C12—C17	117.82 (16)	C45—C44—H44	120.4
C14—C13—C12	120.59 (18)	C43—C44—H44	120.4
C14—C13—H13	119.7	C44—C45—C46	119.64 (19)
C12—C13—H13	119.7	C44—C45—H45	120.2
C15—C14—C13	119.22 (18)	C46—C45—H45	120.2
C15—C14—H14	120.4	C45—C46—C41	123.37 (17)
C13—C14—H14	120.4	C45—C46—H46	118.3
C14—C15—C16	120.06 (18)	C41—C46—H46	118.3
C14—C15—H15	120.0	N4—C47—C42	109.33 (14)
C16—C15—H15	120.0	N4—C47—H47A	109.8
C15—C16—C11	122.83 (17)	C42—C47—H47A	109.8
C15—C16—H16	118.6	N4—C47—H47B	109.8
C11—C16—H16	118.6	C42—C47—H47B	109.8
N1—C17—C12	108.77 (14)	H47A—C47—H47B	108.3
N1—C17—H17A	109.9	N4—C48—H48A	109.5
C12—C17—H17A	109.9	N4—C48—H48B	109.5
N1—C17—H17B	109.9	H48A—C48—H48B	109.5
C12—C17—H17B	109.9	N4—C48—H48C	109.5
H17A—C17—H17B	108.3	H48A—C48—H48C	109.5
N1—C18—H18A	109.5	H48B—C48—H48C	109.5
N1—C18—H18B	109.5	N4—C49—H49A	109.5
H18A—C18—H18B	109.5	N4—C49—H49B	109.5
N1—C18—H18C	109.5	H49A—C49—H49B	109.5
H18A—C18—H18C	109.5	N4—C49—H49C	109.5
H18B—C18—H18C	109.5	H49A—C49—H49C	109.5
N1—C19—H19A	109.5	H49B—C49—H49C	109.5
N1—C19—H19B	109.5	C1—O1—C4	109.7 (3)
H19A—C19—H19B	109.5	O1—C1—C2	106.3 (4)
N1—C19—H19C	109.5	O1—C1—H1A	110.5
H19A—C19—H19C	109.5	C2—C1—H1A	110.5
H19B—C19—H19C	109.5	O1—C1—H1B	110.5
C29—N2—C28	109.45 (16)	C2—C1—H1B	110.5
C29—N2—C27	110.83 (16)	H1A—C1—H1B	108.7
C28—N2—C27	110.47 (15)	C1—C2—C3	101.3 (4)
C29—N2—Cu2	116.42 (12)	C1—C2—H2A	111.5
C28—N2—Cu2	107.02 (12)	C3—C2—H2A	111.5
C27—N2—Cu2	102.39 (11)	C1—C2—H2B	111.5
C26—C21—C22	115.53 (17)	C3—C2—H2B	111.5
C26—C21—Cu3	113.02 (13)	H2A—C2—H2B	109.3
C22—C21—Cu3	122.85 (14)	C4—C3—C2	101.8 (4)
C26—C21—Cu2	122.35 (13)	C4—C3—H3A	111.4
C22—C21—Cu2	104.04 (12)	C2—C3—H3A	111.4
Cu3—C21—Cu2	72.08 (6)	C4—C3—H3B	111.4
C23—C22—C21	121.8 (2)	C2—C3—H3B	111.4
C23—C22—C27	120.99 (18)	H3A—C3—H3B	109.3
C21—C22—C27	117.05 (16)	O1—C4—C3	107.7 (4)
C24—C23—C22	120.3 (2)	O1—C4—H4A	110.2
C24—C23—H23	119.8	C3—C4—H4A	110.2
C22—C23—H23	119.8	O1—C4—H4B	110.2
C25—C24—C23	119.86 (19)	C3—C4—H4B	110.2
C25—C24—H24	120.1	H4A—C4—H4B	108.5
C23—C24—H24	120.1	C1A—O1A—C4A	110.0 (3)
C24—C25—C26	119.7 (2)	O1A—C1A—C2A	106.8 (4)
C24—C25—H25	120.1	O1A—C1A—H1C	110.4
C26—C25—H25	120.1	C2A—C1A—H1C	110.4
C25—C26—C21	122.69 (19)	O1A—C1A—H1D	110.4
C25—C26—H26	118.7	C2A—C1A—H1D	110.4
C21—C26—H26	118.7	H1C—C1A—H1D	108.6
N2—C27—C22	109.06 (15)	C1A—C2A—C3A	101.3 (4)
N2—C27—H27A	109.9	C1A—C2A—H2C	111.5
C22—C27—H27A	109.9	C3A—C2A—H2C	111.5
N2—C27—H27B	109.9	C1A—C2A—H2D	111.5
C22—C27—H27B	109.9	C3A—C2A—H2D	111.5
H27A—C27—H27B	108.3	H2C—C2A—H2D	109.3
N2—C28—H28A	109.5	C4A—C3A—C2A	101.5 (4)
N2—C28—H28B	109.5	C4A—C3A—H3C	111.5
H28A—C28—H28B	109.5	C2A—C3A—H3C	111.5
N2—C28—H28C	109.5	C4A—C3A—H3D	111.5
H28A—C28—H28C	109.5	C2A—C3A—H3D	111.5
H28B—C28—H28C	109.5	H3C—C3A—H3D	109.3
N2—C29—H29A	109.5	O1A—C4A—C3A	107.4 (4)
N2—C29—H29B	109.5	O1A—C4A—H4C	110.2
H29A—C29—H29B	109.5	C3A—C4A—H4C	110.2
N2—C29—H29C	109.5	O1A—C4A—H4D	110.2
H29A—C29—H29C	109.5	C3A—C4A—H4D	110.2
H29B—C29—H29C	109.5	H4C—C4A—H4D	108.5
C41—Cu1—Cu2—C11	141.19 (10)	Cu4—Cu3—C21—C26	81.23 (15)
N1—Cu1—Cu2—C11	−75.53 (7)	Cu2—Cu3—C21—C26	118.27 (15)
Cu4—Cu1—Cu2—C11	114.19 (6)	Cu1—Cu3—C21—C26	76.70 (13)
Cu3—Cu1—Cu2—C11	149.86 (6)	C31—Cu3—C21—C22	−26.5 (3)
C41—Cu1—Cu2—C21	−53.28 (10)	N3—Cu3—C21—C22	90.82 (15)
C11—Cu1—Cu2—C21	165.53 (8)	Cu4—Cu3—C21—C22	−132.47 (12)
N1—Cu1—Cu2—C21	90.00 (7)	Cu2—Cu3—C21—C22	−95.44 (15)
Cu4—Cu1—Cu2—C21	−80.28 (5)	Cu1—Cu3—C21—C22	−137.01 (14)
Cu3—Cu1—Cu2—C21	−44.61 (5)	C31—Cu3—C21—Cu2	68.98 (17)
C41—Cu1—Cu2—N2	88.7 (2)	N3—Cu3—C21—Cu2	−173.74 (5)
C11—Cu1—Cu2—N2	−52.45 (19)	Cu4—Cu3—C21—Cu2	−37.03 (10)
N1—Cu1—Cu2—N2	−127.98 (18)	Cu1—Cu3—C21—Cu2	−41.57 (4)
Cu4—Cu1—Cu2—N2	61.74 (18)	C11—Cu2—C21—C26	−9.9 (3)
Cu3—Cu1—Cu2—N2	97.41 (18)	N2—Cu2—C21—C26	142.61 (15)
C41—Cu1—Cu2—Cu3	−8.67 (8)	Cu1—Cu2—C21—C26	−46.16 (15)
C11—Cu1—Cu2—Cu3	−149.86 (6)	Cu3—Cu2—C21—C26	−106.37 (16)
N1—Cu1—Cu2—Cu3	134.61 (4)	C11—Cu2—C21—C22	−143.09 (17)
Cu4—Cu1—Cu2—Cu3	−35.670 (9)	N2—Cu2—C21—C22	9.42 (12)
C11—Cu2—Cu3—C21	−153.44 (9)	Cu1—Cu2—C21—C22	−179.34 (11)
N2—Cu2—Cu3—C21	73.49 (8)	Cu3—Cu2—C21—C22	120.45 (14)
Cu1—Cu2—Cu3—C21	−121.12 (6)	C11—Cu2—C21—Cu3	96.46 (18)
C11—Cu2—Cu3—C31	51.35 (8)	N2—Cu2—C21—Cu3	−111.02 (6)
C21—Cu2—Cu3—C31	−155.20 (8)	Cu1—Cu2—C21—Cu3	60.21 (5)
N2—Cu2—Cu3—C31	−81.72 (7)	C26—C21—C22—C23	2.1 (3)
Cu1—Cu2—Cu3—C31	83.68 (5)	Cu3—C21—C22—C23	−143.47 (15)
C11—Cu2—Cu3—N3	−133.66 (15)	Cu2—C21—C22—C23	139.00 (15)
C21—Cu2—Cu3—N3	19.79 (15)	C26—C21—C22—C27	−174.02 (16)
N2—Cu2—Cu3—N3	93.28 (14)	Cu3—C21—C22—C27	40.5 (2)
Cu1—Cu2—Cu3—N3	−101.33 (13)	Cu2—C21—C22—C27	−37.07 (18)
C11—Cu2—Cu3—Cu4	3.42 (7)	C21—C22—C23—C24	−0.1 (3)
C21—Cu2—Cu3—Cu4	156.86 (7)	C27—C22—C23—C24	175.79 (19)
N2—Cu2—Cu3—Cu4	−129.65 (4)	C22—C23—C24—C25	−1.4 (3)
Cu1—Cu2—Cu3—Cu4	35.741 (9)	C23—C24—C25—C26	0.9 (3)
C11—Cu2—Cu3—Cu1	−32.32 (7)	C24—C25—C26—C21	1.2 (3)
C21—Cu2—Cu3—Cu1	121.12 (6)	C22—C21—C26—C25	−2.6 (3)
N2—Cu2—Cu3—Cu1	−165.39 (5)	Cu3—C21—C26—C25	146.29 (16)
C41—Cu1—Cu3—C21	−140.39 (7)	Cu2—C21—C26—C25	−130.98 (17)
C11—Cu1—Cu3—C21	68.48 (7)	C29—N2—C27—C22	−163.57 (15)
N1—Cu1—Cu3—C21	−26.23 (8)	C28—N2—C27—C22	74.94 (19)
Cu4—Cu1—Cu3—C21	176.19 (5)	Cu2—N2—C27—C22	−38.76 (16)
Cu2—Cu1—Cu3—C21	45.02 (5)	C23—C22—C27—N2	−120.41 (18)
C41—Cu1—Cu3—C31	62.74 (7)	C21—C22—C27—N2	55.7 (2)
C11—Cu1—Cu3—C31	−88.39 (7)	C21—Cu3—N3—C38	62.36 (14)
N1—Cu1—Cu3—C31	176.90 (7)	C31—Cu3—N3—C38	−139.30 (14)
Cu4—Cu1—Cu3—C31	19.32 (5)	Cu4—Cu3—N3—C38	−90.28 (13)
Cu2—Cu1—Cu3—C31	−111.84 (5)	Cu2—Cu3—N3—C38	45.3 (2)
C41—Cu1—Cu3—N3	−28.74 (7)	Cu1—Cu3—N3—C38	−40.94 (15)
C11—Cu1—Cu3—N3	−179.87 (7)	C21—Cu3—N3—C39	−59.24 (14)
N1—Cu1—Cu3—N3	85.41 (8)	C31—Cu3—N3—C39	99.10 (13)
Cu4—Cu1—Cu3—N3	−72.17 (5)	Cu4—Cu3—N3—C39	148.12 (11)
Cu2—Cu1—Cu3—N3	156.67 (5)	Cu2—Cu3—N3—C39	−76.27 (18)
C41—Cu1—Cu3—Cu4	43.43 (5)	Cu1—Cu3—N3—C39	−162.54 (10)
C11—Cu1—Cu3—Cu4	−107.71 (5)	C21—Cu3—N3—C37	−176.03 (11)
N1—Cu1—Cu3—Cu4	157.58 (6)	C31—Cu3—N3—C37	−17.69 (11)
Cu2—Cu1—Cu3—Cu4	−131.163 (12)	Cu4—Cu3—N3—C37	31.32 (11)
C41—Cu1—Cu3—Cu2	174.59 (5)	Cu2—Cu3—N3—C37	166.93 (10)
C11—Cu1—Cu3—Cu2	23.46 (5)	Cu1—Cu3—N3—C37	80.66 (11)
N1—Cu1—Cu3—Cu2	−71.26 (5)	C41—Cu4—C31—C36	−171.14 (14)
Cu4—Cu1—Cu3—Cu2	131.163 (12)	N4—Cu4—C31—C36	53.77 (14)
C21—Cu3—Cu4—C31	149.71 (10)	Cu3—Cu4—C31—C36	−114.67 (14)
N3—Cu3—Cu4—C31	−72.55 (7)	Cu1—Cu4—C31—C36	−82.68 (14)
Cu2—Cu3—Cu4—C31	119.87 (6)	C41—Cu4—C31—C32	38.0 (3)
Cu1—Cu3—Cu4—C31	155.56 (6)	N4—Cu4—C31—C32	−97.11 (15)
C21—Cu3—Cu4—C41	−50.23 (10)	Cu3—Cu4—C31—C32	94.44 (15)
C31—Cu3—Cu4—C41	160.06 (8)	Cu1—Cu4—C31—C32	126.43 (13)
N3—Cu3—Cu4—C41	87.51 (6)	C41—Cu4—C31—Cu3	−56.46 (18)
Cu2—Cu3—Cu4—C41	−80.07 (5)	N4—Cu4—C31—Cu3	168.45 (5)
Cu1—Cu3—Cu4—C41	−44.38 (5)	Cu1—Cu4—C31—Cu3	31.99 (7)
C21—Cu3—Cu4—N4	105.18 (18)	C21—Cu3—C31—C36	−18.1 (3)
C31—Cu3—Cu4—N4	−44.53 (17)	N3—Cu3—C31—C36	−139.65 (14)
N3—Cu3—Cu4—N4	−117.08 (16)	Cu4—Cu3—C31—C36	109.19 (15)
Cu2—Cu3—Cu4—N4	75.34 (16)	Cu2—Cu3—C31—C36	38.81 (15)
Cu1—Cu3—Cu4—N4	111.03 (16)	Cu1—Cu3—C31—C36	90.18 (14)
C21—Cu3—Cu4—Cu1	−5.85 (8)	C21—Cu3—C31—C32	112.27 (18)
C31—Cu3—Cu4—Cu1	−155.56 (6)	N3—Cu3—C31—C32	−9.29 (12)
N3—Cu3—Cu4—Cu1	131.89 (4)	Cu4—Cu3—C31—C32	−120.45 (13)
Cu2—Cu3—Cu4—Cu1	−35.685 (9)	Cu2—Cu3—C31—C32	169.17 (10)
C41—Cu1—Cu4—C31	−150.91 (9)	Cu1—Cu3—C31—C32	−139.46 (11)
C11—Cu1—Cu4—C31	58.16 (8)	C21—Cu3—C31—Cu4	−127.28 (14)
N1—Cu1—Cu4—C31	−137.50 (15)	N3—Cu3—C31—Cu4	111.16 (6)
Cu2—Cu1—Cu4—C31	8.99 (7)	Cu2—Cu3—C31—Cu4	−70.38 (5)
Cu3—Cu1—Cu4—C31	−27.16 (7)	Cu1—Cu3—C31—Cu4	−19.01 (5)
C11—Cu1—Cu4—C41	−150.94 (8)	C36—C31—C32—C33	−4.3 (3)
N1—Cu1—Cu4—C41	13.41 (15)	Cu4—C31—C32—C33	146.81 (16)
Cu2—Cu1—Cu4—C41	159.90 (6)	Cu3—C31—C32—C33	−137.58 (17)
Cu3—Cu1—Cu4—C41	123.75 (6)	C36—C31—C32—C37	170.52 (16)
C41—Cu1—Cu4—N4	71.33 (8)	Cu4—C31—C32—C37	−38.4 (2)
C11—Cu1—Cu4—N4	−79.61 (7)	Cu3—C31—C32—C37	37.24 (18)
N1—Cu1—Cu4—N4	84.74 (14)	C31—C32—C33—C34	2.4 (3)
Cu2—Cu1—Cu4—N4	−128.77 (5)	C37—C32—C33—C34	−172.2 (2)
Cu3—Cu1—Cu4—N4	−164.92 (5)	C32—C33—C34—C35	1.5 (3)
C41—Cu1—Cu4—Cu3	−123.75 (6)	C33—C34—C35—C36	−3.2 (3)
C11—Cu1—Cu4—Cu3	85.32 (5)	C34—C35—C36—C31	1.1 (3)
N1—Cu1—Cu4—Cu3	−110.34 (14)	C32—C31—C36—C35	2.6 (3)
Cu2—Cu1—Cu4—Cu3	36.152 (9)	Cu4—C31—C36—C35	−150.67 (16)
C41—Cu1—N1—C18	74.87 (14)	Cu3—C31—C36—C35	127.97 (17)
C11—Cu1—N1—C18	−131.51 (13)	C38—N3—C37—C32	165.68 (15)
Cu4—Cu1—N1—C18	63.3 (2)	C39—N3—C37—C32	−73.51 (18)
Cu2—Cu1—N1—C18	−82.04 (13)	Cu3—N3—C37—C32	40.06 (15)
Cu3—Cu1—N1—C18	−32.17 (15)	C33—C32—C37—N3	118.25 (19)
C41—Cu1—N1—C19	−47.55 (13)	C31—C32—C37—N3	−56.6 (2)
C11—Cu1—N1—C19	106.06 (12)	C31—Cu4—N4—C49	−56.73 (14)
Cu4—Cu1—N1—C19	−59.1 (2)	C41—Cu4—N4—C49	139.23 (14)
Cu2—Cu1—N1—C19	155.53 (11)	Cu3—Cu4—N4—C49	−17.4 (2)
Cu3—Cu1—N1—C19	−154.60 (10)	Cu1—Cu4—N4—C49	89.88 (13)
C41—Cu1—N1—C17	−163.29 (10)	C31—Cu4—N4—C48	65.18 (15)
C11—Cu1—N1—C17	−9.67 (11)	C41—Cu4—N4—C48	−98.85 (14)
Cu4—Cu1—N1—C17	−174.88 (10)	Cu3—Cu4—N4—C48	104.49 (19)
Cu2—Cu1—N1—C17	39.79 (10)	Cu1—Cu4—N4—C48	−148.21 (13)
Cu3—Cu1—N1—C17	89.66 (11)	C31—Cu4—N4—C47	−178.24 (11)
C21—Cu2—C11—C16	−156.01 (16)	C41—Cu4—N4—C47	17.73 (11)
N2—Cu2—C11—C16	53.90 (14)	Cu3—Cu4—N4—C47	−138.93 (13)
Cu1—Cu2—C11—C16	−113.85 (13)	Cu1—Cu4—N4—C47	−31.63 (11)
Cu3—Cu2—C11—C16	−75.89 (13)	C11—Cu1—C41—C46	−173.44 (12)
C21—Cu2—C11—C12	41.3 (3)	N1—Cu1—C41—C46	−56.19 (13)
N2—Cu2—C11—C12	−108.80 (16)	Cu4—Cu1—C41—C46	119.67 (13)
Cu1—Cu2—C11—C12	83.45 (15)	Cu2—Cu1—C41—C46	86.36 (14)
Cu3—Cu2—C11—C12	121.41 (14)	Cu3—Cu1—C41—C46	79.58 (12)
C21—Cu2—C11—Cu1	−42.2 (2)	C11—Cu1—C41—C42	−28.6 (2)
N2—Cu2—C11—Cu1	167.75 (5)	N1—Cu1—C41—C42	88.66 (16)
Cu3—Cu2—C11—Cu1	37.97 (7)	Cu4—Cu1—C41—C42	−95.47 (16)
C41—Cu1—C11—C16	−20.8 (2)	Cu2—Cu1—C41—C42	−128.78 (13)
N1—Cu1—C11—C16	−142.69 (14)	Cu3—Cu1—C41—C42	−135.56 (16)
Cu4—Cu1—C11—C16	32.71 (14)	C11—Cu1—C41—Cu4	66.89 (14)
Cu2—Cu1—C11—C16	107.44 (15)	N1—Cu1—C41—Cu4	−175.86 (5)
Cu3—Cu1—C11—C16	84.00 (13)	Cu2—Cu1—C41—Cu4	−33.31 (10)
C41—Cu1—C11—C12	103.50 (16)	Cu3—Cu1—C41—Cu4	−40.09 (3)
N1—Cu1—C11—C12	−18.38 (11)	C31—Cu4—C41—C46	4.2 (3)
Cu4—Cu1—C11—C12	157.03 (9)	N4—Cu4—C41—C46	142.85 (15)
Cu2—Cu1—C11—C12	−128.25 (12)	Cu3—Cu4—C41—C46	−43.54 (15)
Cu3—Cu1—C11—C12	−151.68 (10)	Cu1—Cu4—C41—C46	−102.58 (15)
C41—Cu1—C11—Cu2	−128.25 (12)	C31—Cu4—C41—C42	−130.83 (17)
N1—Cu1—C11—Cu2	109.87 (5)	N4—Cu4—C41—C42	7.77 (12)
Cu4—Cu1—C11—Cu2	−74.72 (4)	Cu3—Cu4—C41—C42	−178.62 (10)
Cu3—Cu1—C11—Cu2	−23.43 (4)	Cu1—Cu4—C41—C42	122.34 (13)
C16—C11—C12—C13	0.1 (2)	C31—Cu4—C41—Cu1	106.83 (16)
Cu2—C11—C12—C13	162.69 (14)	N4—Cu4—C41—Cu1	−114.57 (6)
Cu1—C11—C12—C13	−126.84 (16)	Cu3—Cu4—C41—Cu1	59.04 (5)
C16—C11—C12—C17	175.05 (15)	C46—C41—C42—C43	1.6 (3)
Cu2—C11—C12—C17	−22.4 (2)	Cu1—C41—C42—C43	−141.76 (15)
Cu1—C11—C12—C17	48.06 (16)	Cu4—C41—C42—C43	140.93 (15)
C11—C12—C13—C14	−1.1 (3)	C46—C41—C42—C47	−173.95 (15)
C17—C12—C13—C14	−175.91 (16)	Cu1—C41—C42—C47	42.7 (2)
C12—C13—C14—C15	1.0 (3)	Cu4—C41—C42—C47	−34.62 (18)
C13—C14—C15—C16	0.1 (3)	C41—C42—C43—C44	1.0 (3)
C14—C15—C16—C11	−1.2 (3)	C47—C42—C43—C44	176.30 (17)
C12—C11—C16—C15	1.0 (2)	C42—C43—C44—C45	−2.9 (3)
Cu2—C11—C16—C15	−164.07 (13)	C43—C44—C45—C46	2.2 (3)
Cu1—C11—C16—C15	115.93 (16)	C44—C45—C46—C41	0.5 (3)
C18—N1—C17—C12	161.03 (15)	C42—C41—C46—C45	−2.4 (3)
C19—N1—C17—C12	−77.36 (18)	Cu1—C41—C46—C45	146.16 (15)
Cu1—N1—C17—C12	34.92 (15)	Cu4—C41—C46—C45	−133.35 (16)
C13—C12—C17—N1	111.54 (18)	C49—N4—C47—C42	−163.90 (15)
C11—C12—C17—N1	−63.46 (19)	C48—N4—C47—C42	73.64 (18)
C11—Cu2—N2—C29	−52.54 (16)	Cu4—N4—C47—C42	−38.90 (15)
C21—Cu2—N2—C29	137.79 (15)	C43—C42—C47—N4	−121.82 (18)
Cu1—Cu2—N2—C29	−5.7 (3)	C41—C42—C47—N4	53.7 (2)
Cu3—Cu2—N2—C29	88.35 (14)	C4—O1—C1—C2	25.0 (6)
C11—Cu2—N2—C28	70.20 (13)	O1—C1—C2—C3	−36.0 (5)
C21—Cu2—N2—C28	−99.47 (13)	C1—C2—C3—C4	32.4 (4)
Cu1—Cu2—N2—C28	117.01 (18)	C1—O1—C4—C3	−3.0 (6)
Cu3—Cu2—N2—C28	−148.91 (11)	C2—C3—C4—O1	−19.3 (5)
C11—Cu2—N2—C27	−173.58 (12)	C4A—O1A—C1A—C2A	20.6 (10)
C21—Cu2—N2—C27	16.75 (12)	O1A—C1A—C2A—C3A	−34.2 (7)
Cu1—Cu2—N2—C27	−126.77 (16)	C1A—C2A—C3A—C4A	33.6 (5)
Cu3—Cu2—N2—C27	−32.69 (12)	C1A—O1A—C4A—C3A	2.2 (10)
C31—Cu3—C21—C26	−172.75 (14)	C2A—C3A—C4A—O1A	−23.2 (8)
N3—Cu3—C21—C26	−55.47 (14)