Acta Cryst. (2005). E61, m1073-m1074  [ doi:10.1107/S1600536805013516 ]

Dicarbonyl(⁵-cyclopentadienyl)(trimethylsilyl isocyanide)iron(II) trifluoromethanesulfonate

H. Nakazawa, M. Itazaki and M. Owaribe

Abstract: In the title compound, [Fe(C₅H₅)(C₄H₉NSi)(CO)₂](CF₃SO₃), the Fe atom is coordinated by two carbonyl groups, a trimethylsilylisocyanide ligand and a cyclopentadienyl ligand in a typical piano-stool structure. The Fe-CN, CN and CN-Si bond distances are 1.862 (4), 1.157 (6) and 1.794 (4) Å, respectively, and the Fe-C-N-Si arrangement is almost linear.

Online 14 May 2005

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