Acta Cryst. (2005). E61, i116-i119  [ doi:10.1107/S1600536805016211 ]

Europium antimony sulfide, Eu₆Sb₆S₁₇

G. Jin, D. M. Wells, S. J. Crerar, T. C. Shehee, A. Mar and T. E. Albrecht-Schmitt

Abstract: Eu₆Sb₆S₁₇ is isotypic with Sr₆Sb₆S₁₇ and can be regarded as consisting of two isolated [Sb₃S₇]^5- anions and an S₃^2- polysulfide anion that are joined together by Eu²⁺ cations. There are six crystallographically unique Eu²⁺ cations bound by sulfide and polysulfide anions in seven-, eight- and nine-coordinate environments. Each of the [Sb₃S₇]^5- anions consists of a trinuclear assembly of corner-sharing SbS₃ units. The [Sb₃S₇]^5- anions are connected by long (3.1 Å) Sb-S interactions, forming one-dimensional ribbons running down the a axis and packed with opposing directions of polarity. The bent S₃^2- anions stack in columns parallel to the a axis, oriented in opposing directions with respect to one another. The overall structure is three-dimensional and has channels running down the a axis to house the stereochemically active lone pair of electrons on the Sb³⁺ centers. The presence of Eu²⁺ is supported by both magnetic measurements and bond-valence calculations.

Online 28 May 2005

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