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Acta Cryst. (2005). E61, m1234-m1236  [ doi:10.1107/S1600536805016016 ]

Poly[[(1,10-phenanthroline-[kappa]2N,N')cadmium(II)]-[mu]3-pyridine-3,4-dicarboxylato-[kappa]5N:O,O':O'',O''']

X.-L. Wang, C. Qin and E.-B. Wang

Abstract: In the title compound, [Cd(C7H3NO4)(C12H8N2)]n, the CdII atom has a distorted pentagonal bipyramidal coordination geometry, defined by three N atoms and four carboxyl O atoms from chelating 1,10-phenanthroline and pyridine-3,4-dicarboxylate ligands. The structure exhibits a novel two-dimensional wave-like layer parallel to the (110) plane, with (6,3)-topology, which further forms a three-dimensional supramolecular network via [pi]-[pi] stacking.

Online 28 May 2005


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