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Acta Cryst. (2005). E61, m1280-m1282  [ doi:10.1107/S1600536805015850 ]

[N,N'-Diphenylureato(2-)][phthalocyaninato(2-)]titanium(IV)

W. Darwish, K. Harms and J. Sundermeyer

Abstract: In the title complex, [Ti(C32H16N8)(C13H10N2O)], the geometry around the Ti atom is square pyramidal, with the four isoindoline N atoms forming the basal plane and the ureate group at the apical site. The crystal structure is formed by close packing of centrosymmetric dimers, consisting of slightly offset molecules related by a crystallographic center of inversion in a face-to-face manner.

Online 10 June 2005


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