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Acta Cryst. (2005). E61, o2239-o2240  [ doi:10.1107/S1600536805019136 ]

4,4'-Bipyridine-5-amino-1,3,4-thiadiazole-2(3H)-thione (1/2)

Q.-J. Deng, M.-X. Yao and M.-H. Zeng

Abstract: In the title complex, C10H8N2·2C2H3N3S2, the 4,4'-bipyridine (bpy) molecule, lying on an inversion centre, is connected to two 5-amino-1,3,4-thiadiazole-2(3H)-thione (tdz) molecules through N-H...N hydrogen bonds. The tdz planes are slightly twisted with respect to the bpy plane, with a dihedral angle of 2.1  (2)°. Further intermolecular N-H...N and N-H...S hydrogen bonds result in a three-dimensional network structure.

Online 24 June 2005


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