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Acta Cryst. (2005). E61, m1266-m1268 [ doi:10.1107/S1600536805017095 ]
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5,5-propane-2,2-diyldicyclopentadienyl)titanium(IV)Abstract: In the title compound, [Ti(C13H14)F2], the coordination polyhedron around the Ti atom is a distorted tetrahedron defined by the centroids of the cyclopentadienyl rings and the two F atoms. The Ti-ring centroid (Cg) distances are 2.0558 (7) and 2.0567 (8) Å. The presence of a short carbon bridge linking the cyclopentadienyl rings constrains the Cg-Ti-Cg angle to a value of 121.50 (3)°.
Online 10 June 2005
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