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Acta Cryst. (2005). E61, m1283-m1285  [ doi:10.1107/S1600536805017447 ]

trans-Carbonylchlorobis[tris(pentafluorophenyl)phosphine)]rhodium(I)

R. Meijboom, A. Muller and A. Roodt

Abstract: The title compound, trans-[RhCl(C18F15P)2(CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 (14) and 2.2993 (14) Å, Rh-Cl = 2.3642 (12) Å, Rh-C = 1.824 (4) Å, C-Rh-Cl = 174.12 (13)°, P-Rh-C = 91.73 (13) and 93.71 (13)°, P-Rh-P = 169.38 (4)° and Rh-C[triple bond]O = 176.7 (4)°. The effective cone angles ([theta]E) for the phosphine ligands were calculated to be 172 and 173°.

Online 10 June 2005


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