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Acta Cryst. (2005). E61, m1329-m1331 [ doi:10.1107/S1600536805017903 ]
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2-![[eta]](/logos/entities/eta_rmgif.gif)
2-2-tert-Butylethyn-1-yl)(2-chloro)bis{[bis(5-cyclopentadienyl)dimethylsilane]titanium}Abstract: The title compound, [Ti2Cl(C6H9)(C12H14Si)2], displays an asymmetric 2-2 C![[triple bond]](/logos/entities/z-tbnd_rmgif.gif)
C bridge between the two metal ions. The C-CC bond angle deviates markedly from linearity. The difference in the Ti-Cl bond lengths involving the bridging Cl is 0.146 (3) Å. The angles between the least-squares planes through the ring systems of the titanocene units are 55.4 (4) and 57.8 (4)°.
Online 17 June 2005
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