Acta Cryst. (2005). E61, m1398-m1400  [ doi:10.1107/S160053680501932X ]

(2-Methylpropane-1,2-diamine-²N,N')[tris(2-aminoethyl)amine-⁴N,N',N'',N''']nickel(II) diperchlorate

Y.-C. Lin, T.-H. Lu, C.-Y. Li, F.-L. Liao and C.-S. Chung

Abstract: In the title compound, [N(C₄H₁₂N₂)(C₆H₁₈N₄)](ClO₄)₂, the Ni^II atom is coordinated in a distorted octahedron by four N atoms of the tris(2-aminoethyl)amine (tren) ligand and by two N atoms of the 2-methylpropane-1,2-diamine (2-Mepn) ligand. The primary amino group of 2-Mepn at the C-2 position occupies the position trans to the tertiary amino group of tren. The complex cations and perchlorate anions are linked via N-HO hydrogen bonds, forming one-dimensional zigzag chains along the [101] direction.

Online 24 June 2005

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