Acta Cryst. (2005). E61, m1324-m1325  [ doi:10.1107/S1600536805018325 ]

A dinuclear chloro(triphenylphosphito)copper(I) complex, di-₂-chloro-bis[bis(triphenylphosphito)copper(I)]

F.-F. Jian, K.-F. Wang, H.-L. Xiao and Y.-B. Qiao

Online 17 June 2005

Key indicators

• Single-crystal X-ray study
• T = 295 K
• Mean (C-C) = 0.008 Å
• R factor = 0.052
• wR factor = 0.146
• Data-to-parameter ratio = 17.7

checkCIF/PLATON results

No syntax errors found




Alert level B
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for        C33     
PLAT331_ALERT_2_B Small Average Phenyl C-C Dist.   C31    -C36           1.36 Ang.  

Alert level C
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.47 Ratio 
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Cu1    -   Cl1     ..       8.10 su    
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Cu1    -   P2      ..       5.08 su    
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Cu1    -   Cl1_a   ..       7.49 su    
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         C5     
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C21     
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C29     
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C31     
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C34     
PLAT331_ALERT_2_C Small Average Phenyl C-C Dist.   C1     -C6            1.37 Ang.  
PLAT331_ALERT_2_C Small Average Phenyl C-C Dist.   C7     -C12           1.37 Ang.  
PLAT331_ALERT_2_C Small Average Phenyl C-C Dist.   C25    -C30           1.37 Ang.  
PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...          8       

   0 ALERT level A = In general: serious problem
   2 ALERT level B = Potentially serious problem
  13 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  14 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion

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