In the title compound, [MnClL2]Cl·3CH4O, where L = bis(benzimidazol-2-ylmethyl)amine (C16H15N5), the coordination geometry around the manganese(II) ion can be described as distorted octahedral, involving three benzimidazole N atoms, two tertiary amine atoms and a chloride anion. π–π Stacking interactions are found in two neighboring non-coordinated benzimidazole groups.
Supporting information
CCDC reference: 277815
Key indicators
- Single-crystal X-ray study
- T = 203 K
- Mean (C-C) = 0.006 Å
- R factor = 0.049
- wR factor = 0.071
- Data-to-parameter ratio = 14.0
checkCIF/PLATON results
No syntax errors found
Datablock: I
Alert level C
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ?
PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.12 Ratio
PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.69 Ratio
PLAT230_ALERT_2_C Hirshfeld Test Diff for C31 - C32 .. 5.45 su
PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C24
0 ALERT level A = In general: serious problem
0 ALERT level B = Potentially serious problem
5 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
3 ALERT type 2 Indicator that the structure model may be wrong or deficient
1 ALERT type 3 Indicator that the structure quality may be low
0 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: SMART (Bruker, 1998); cell refinement: SMART; data reduction: SAINT (Bruker, 1998); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1998); software used to prepare material for publication: SHELXTL.
dichloro[bis(bis(benzimidazol-2-ylmethyl)-amine)] manganese(II) methanol
trisolvate
top
Crystal data top
[Mn(C16H15N5)2Cl]Cl·3CH4O | F(000) = 1620 |
Mr = 776.63 | Dx = 1.325 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2ybc | Cell parameters from 2271 reflections |
a = 13.161 (3) Å | θ = 2.3–20.7° |
b = 11.905 (3) Å | µ = 0.52 mm−1 |
c = 25.144 (7) Å | T = 203 K |
β = 98.794 (4)° | Block, colorless |
V = 3893.2 (17) Å3 | 0.40 × 0.30 × 0.10 mm |
Z = 4 | |
Data collection top
Bruker SMART CCD area-detector diffractometer | 6860 independent reflections |
Radiation source: fine-focus sealed tube | 3596 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.051 |
φ and ω scans | θmax = 25.0°, θmin = 1.6° |
Absorption correction: multi-scan (SADABS; Bruker, 1998) | h = −15→7 |
Tmin = 0.818, Tmax = 0.950 | k = −14→14 |
15680 measured reflections | l = −29→29 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.049 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.071 | H atoms treated by a mixture of independent and constrained refinement |
S = 0.93 | w = 1/[σ2(Fo2) + (0.0102P)2] where P = (Fo2 + 2Fc2)/3 |
6860 reflections | (Δ/σ)max = 0.001 |
490 parameters | Δρmax = 0.48 e Å−3 |
4 restraints | Δρmin = −0.36 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
C1 | 0.6249 (3) | 0.8793 (3) | 0.55043 (15) | 0.0453 (9) | |
C2 | 0.6099 (3) | 0.9134 (3) | 0.49718 (16) | 0.0597 (11) | |
H2 | 0.6233 | 0.9868 | 0.4876 | 0.072* | |
C3 | 0.5744 (3) | 0.8344 (3) | 0.45905 (15) | 0.0660 (12) | |
H3 | 0.5633 | 0.8543 | 0.4229 | 0.079* | |
C4 | 0.5547 (3) | 0.7242 (3) | 0.47399 (16) | 0.0585 (11) | |
H4 | 0.5302 | 0.6723 | 0.4475 | 0.070* | |
C5 | 0.5705 (2) | 0.6912 (3) | 0.52646 (15) | 0.0492 (10) | |
H5 | 0.5571 | 0.6178 | 0.5359 | 0.059* | |
C6 | 0.6070 (2) | 0.7697 (3) | 0.56544 (15) | 0.0407 (9) | |
C7 | 0.6581 (2) | 0.8611 (3) | 0.63816 (14) | 0.0395 (9) | |
C8 | 0.6802 (2) | 0.8936 (2) | 0.69596 (13) | 0.0436 (9) | |
H8A | 0.7388 | 0.9440 | 0.7015 | 0.052* | |
H8B | 0.6215 | 0.9332 | 0.7059 | 0.052* | |
C9 | 0.6501 (2) | 0.7944 (2) | 0.77793 (13) | 0.0445 (10) | |
H9A | 0.6493 | 0.8700 | 0.7923 | 0.053* | |
H9B | 0.6865 | 0.7461 | 0.8055 | 0.053* | |
C10 | 0.5426 (3) | 0.7532 (3) | 0.76213 (14) | 0.0374 (9) | |
C11 | 0.3795 (3) | 0.7222 (3) | 0.76310 (15) | 0.0444 (10) | |
C12 | 0.2777 (3) | 0.7177 (3) | 0.77305 (17) | 0.0610 (12) | |
H12 | 0.2564 | 0.7557 | 0.8017 | 0.073* | |
C13 | 0.2113 (3) | 0.6540 (3) | 0.73801 (19) | 0.0654 (13) | |
H13 | 0.1431 | 0.6487 | 0.7433 | 0.079* | |
C14 | 0.2418 (3) | 0.5971 (3) | 0.69497 (16) | 0.0576 (11) | |
H14 | 0.1937 | 0.5564 | 0.6718 | 0.069* | |
C15 | 0.3434 (3) | 0.6003 (3) | 0.68610 (14) | 0.0468 (10) | |
H15 | 0.3647 | 0.5614 | 0.6577 | 0.056* | |
C16 | 0.4120 (3) | 0.6639 (3) | 0.72153 (14) | 0.0378 (9) | |
C17 | 0.6966 (3) | 0.4826 (2) | 0.79777 (14) | 0.0356 (9) | |
C18 | 0.6077 (2) | 0.4871 (2) | 0.82103 (14) | 0.0433 (10) | |
H18 | 0.5507 | 0.5279 | 0.8053 | 0.052* | |
C19 | 0.6067 (3) | 0.4292 (3) | 0.86788 (15) | 0.0502 (10) | |
H19 | 0.5475 | 0.4310 | 0.8838 | 0.060* | |
C20 | 0.6904 (3) | 0.3681 (3) | 0.89263 (14) | 0.0587 (11) | |
H20 | 0.6858 | 0.3292 | 0.9243 | 0.070* | |
C21 | 0.7805 (3) | 0.3642 (3) | 0.87081 (15) | 0.0543 (10) | |
H21 | 0.8377 | 0.3246 | 0.8872 | 0.065* | |
C22 | 0.7809 (3) | 0.4226 (2) | 0.82315 (14) | 0.0383 (9) | |
C23 | 0.8139 (3) | 0.4950 (3) | 0.74777 (14) | 0.0372 (9) | |
C24 | 0.8708 (3) | 0.5171 (3) | 0.70236 (15) | 0.0628 (12) | |
H24A | 0.9349 | 0.5549 | 0.7158 | 0.075* | |
H24B | 0.8873 | 0.4462 | 0.6867 | 0.075* | |
C25 | 0.8115 (3) | 0.5409 (3) | 0.60666 (14) | 0.0570 (11) | |
H25A | 0.7752 | 0.5929 | 0.5808 | 0.068* | |
H25B | 0.7731 | 0.4710 | 0.6037 | 0.068* | |
C26 | 0.9152 (3) | 0.5187 (4) | 0.59121 (15) | 0.0532 (11) | |
C27 | 1.0561 (3) | 0.4407 (4) | 0.57943 (16) | 0.0643 (12) | |
C28 | 1.1382 (4) | 0.3681 (4) | 0.57664 (17) | 0.0949 (16) | |
H28 | 1.1361 | 0.2933 | 0.5871 | 0.114* | |
C29 | 1.2226 (4) | 0.4124 (5) | 0.5577 (2) | 0.111 (2) | |
H29 | 1.2792 | 0.3665 | 0.5561 | 0.133* | |
C30 | 1.2260 (4) | 0.5224 (5) | 0.5410 (2) | 0.1027 (19) | |
H30 | 1.2842 | 0.5484 | 0.5280 | 0.123* | |
C31 | 1.1458 (4) | 0.5939 (4) | 0.54304 (16) | 0.0893 (16) | |
H31 | 1.1478 | 0.6682 | 0.5319 | 0.107* | |
C32 | 1.0615 (3) | 0.5507 (4) | 0.56254 (15) | 0.0614 (12) | |
C33 | 0.7105 (3) | 0.2148 (4) | 0.55188 (19) | 0.1216 (19) | |
H33A | 0.7101 | 0.2912 | 0.5639 | 0.182* | |
H33B | 0.6438 | 0.1954 | 0.5331 | 0.182* | |
H33C | 0.7606 | 0.2064 | 0.5281 | 0.182* | |
C34 | 0.9950 (3) | 0.1629 (4) | 0.6639 (2) | 0.137 (2) | |
H34A | 1.0308 | 0.2026 | 0.6944 | 0.205* | |
H34B | 1.0406 | 0.1502 | 0.6382 | 0.205* | |
H34C | 0.9711 | 0.0922 | 0.6755 | 0.205* | |
C35 | 0.9077 (4) | 0.9133 (4) | 0.5394 (2) | 0.159 (3) | |
H35A | 0.8654 | 0.9674 | 0.5540 | 0.239* | |
H35B | 0.8755 | 0.8918 | 0.5040 | 0.239* | |
H35C | 0.9738 | 0.9458 | 0.5374 | 0.239* | |
Cl1 | 0.07178 (7) | 0.32571 (8) | 0.80441 (5) | 0.0847 (4) | |
Cl2 | 0.55819 (7) | 0.47079 (7) | 0.62765 (4) | 0.0553 (3) | |
H1N | 0.7725 (19) | 0.791 (2) | 0.7422 (11) | 0.036 (10)* | |
H3N | 0.679 (2) | 1.0056 (12) | 0.6049 (11) | 0.047 (11)* | |
H5N | 0.464 (2) | 0.8301 (19) | 0.8147 (9) | 0.063 (13)* | |
H6N | 0.844 (2) | 0.655 (2) | 0.6617 (12) | 0.059 (12)* | |
H8N | 0.9177 (12) | 0.403 (2) | 0.7951 (13) | 0.069 (13)* | |
H10N | 0.952 (2) | 0.6689 (13) | 0.5607 (12) | 0.052 (12)* | |
Mn | 0.64222 (4) | 0.62451 (4) | 0.68032 (2) | 0.03878 (15) | |
N1 | 0.7022 (2) | 0.7940 (2) | 0.73029 (12) | 0.0384 (8) | |
N2 | 0.62919 (19) | 0.7602 (2) | 0.62102 (11) | 0.0383 (7) | |
N3 | 0.6569 (2) | 0.9362 (2) | 0.59732 (13) | 0.0475 (8) | |
N4 | 0.5163 (2) | 0.6842 (2) | 0.72148 (11) | 0.0365 (7) | |
N5 | 0.4643 (3) | 0.7780 (2) | 0.78885 (13) | 0.0465 (8) | |
N6 | 0.8109 (2) | 0.5867 (2) | 0.66074 (12) | 0.0423 (8) | |
N7 | 0.71986 (19) | 0.52869 (19) | 0.74986 (11) | 0.0364 (7) | |
N8 | 0.8551 (2) | 0.4332 (2) | 0.79024 (13) | 0.0424 (8) | |
N9 | 0.9631 (2) | 0.4215 (2) | 0.59725 (12) | 0.0599 (9) | |
N10 | 0.9697 (3) | 0.5982 (3) | 0.57086 (13) | 0.0613 (10) | |
O1 | 0.7341 (3) | 0.1478 (3) | 0.59372 (14) | 0.1097 (12) | |
H1 | 0.7924 | 0.1621 | 0.6088 | 0.164* | |
O2 | 0.9123 (2) | 0.2258 (3) | 0.64050 (18) | 0.1260 (13) | |
H2A | 0.9316 | 0.2722 | 0.6201 | 0.189* | |
O3 | 0.9195 (4) | 0.8228 (3) | 0.57115 (15) | 0.1529 (16) | |
H3A | 0.9244 | 0.8424 | 0.6027 | 0.229* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
C1 | 0.048 (2) | 0.041 (2) | 0.048 (3) | −0.0013 (19) | 0.012 (2) | −0.003 (2) |
C2 | 0.077 (3) | 0.047 (3) | 0.056 (3) | −0.003 (2) | 0.014 (3) | 0.010 (2) |
C3 | 0.085 (3) | 0.067 (3) | 0.047 (3) | 0.003 (2) | 0.012 (2) | 0.002 (3) |
C4 | 0.071 (3) | 0.052 (3) | 0.050 (3) | 0.001 (2) | 0.005 (2) | −0.010 (2) |
C5 | 0.053 (3) | 0.042 (2) | 0.052 (3) | 0.0030 (19) | 0.008 (2) | −0.002 (2) |
C6 | 0.039 (2) | 0.037 (2) | 0.048 (3) | 0.0006 (18) | 0.010 (2) | −0.002 (2) |
C7 | 0.033 (2) | 0.042 (2) | 0.044 (3) | −0.0021 (18) | 0.0086 (19) | −0.002 (2) |
C8 | 0.045 (2) | 0.035 (2) | 0.052 (3) | −0.0030 (17) | 0.011 (2) | −0.003 (2) |
C9 | 0.053 (3) | 0.035 (2) | 0.047 (3) | −0.0011 (18) | 0.010 (2) | −0.0060 (18) |
C10 | 0.040 (3) | 0.030 (2) | 0.044 (3) | 0.0061 (18) | 0.012 (2) | 0.0034 (18) |
C11 | 0.041 (3) | 0.037 (2) | 0.057 (3) | 0.011 (2) | 0.015 (2) | 0.011 (2) |
C12 | 0.056 (3) | 0.052 (3) | 0.081 (4) | 0.018 (2) | 0.031 (3) | 0.023 (2) |
C13 | 0.041 (3) | 0.064 (3) | 0.096 (4) | 0.015 (2) | 0.027 (3) | 0.036 (3) |
C14 | 0.038 (3) | 0.055 (3) | 0.076 (3) | −0.003 (2) | −0.002 (2) | 0.026 (2) |
C15 | 0.040 (2) | 0.045 (2) | 0.054 (3) | 0.0051 (19) | 0.005 (2) | 0.014 (2) |
C16 | 0.034 (2) | 0.032 (2) | 0.047 (3) | 0.0031 (18) | 0.007 (2) | 0.0098 (18) |
C17 | 0.030 (2) | 0.031 (2) | 0.047 (2) | −0.0014 (17) | 0.010 (2) | −0.0067 (18) |
C18 | 0.038 (2) | 0.041 (2) | 0.052 (3) | 0.0017 (18) | 0.010 (2) | 0.000 (2) |
C19 | 0.053 (3) | 0.050 (2) | 0.052 (3) | 0.001 (2) | 0.020 (2) | −0.001 (2) |
C20 | 0.065 (3) | 0.060 (3) | 0.052 (3) | 0.007 (2) | 0.013 (2) | 0.015 (2) |
C21 | 0.047 (3) | 0.055 (3) | 0.059 (3) | 0.012 (2) | 0.003 (2) | 0.004 (2) |
C22 | 0.040 (2) | 0.031 (2) | 0.044 (3) | −0.0017 (18) | 0.008 (2) | −0.0034 (18) |
C23 | 0.035 (2) | 0.036 (2) | 0.041 (2) | 0.0014 (18) | 0.009 (2) | −0.0009 (18) |
C24 | 0.041 (3) | 0.084 (3) | 0.066 (3) | 0.014 (2) | 0.016 (2) | 0.010 (2) |
C25 | 0.048 (3) | 0.060 (3) | 0.065 (3) | 0.009 (2) | 0.014 (2) | −0.008 (2) |
C26 | 0.046 (3) | 0.065 (3) | 0.052 (3) | 0.002 (2) | 0.018 (2) | −0.009 (2) |
C27 | 0.051 (3) | 0.080 (3) | 0.067 (3) | 0.012 (3) | 0.026 (2) | −0.008 (3) |
C28 | 0.075 (4) | 0.116 (4) | 0.102 (4) | 0.030 (3) | 0.039 (3) | −0.008 (3) |
C29 | 0.064 (4) | 0.183 (6) | 0.095 (4) | 0.031 (4) | 0.040 (3) | −0.007 (4) |
C30 | 0.073 (4) | 0.160 (6) | 0.085 (4) | −0.022 (4) | 0.043 (3) | −0.020 (4) |
C31 | 0.087 (4) | 0.112 (4) | 0.075 (4) | −0.022 (3) | 0.033 (3) | −0.029 (3) |
C32 | 0.051 (3) | 0.084 (3) | 0.055 (3) | −0.010 (3) | 0.027 (2) | −0.017 (3) |
C33 | 0.133 (5) | 0.097 (4) | 0.125 (5) | −0.024 (3) | −0.010 (4) | 0.019 (4) |
C34 | 0.120 (5) | 0.138 (5) | 0.153 (6) | 0.059 (4) | 0.022 (4) | 0.060 (4) |
C35 | 0.165 (6) | 0.123 (5) | 0.203 (7) | 0.011 (4) | 0.073 (5) | 0.062 (5) |
Cl1 | 0.0486 (7) | 0.0804 (8) | 0.1281 (11) | 0.0251 (6) | 0.0233 (7) | 0.0153 (7) |
Cl2 | 0.0677 (7) | 0.0433 (5) | 0.0553 (7) | −0.0179 (5) | 0.0110 (6) | −0.0062 (5) |
Mn | 0.0354 (3) | 0.0341 (3) | 0.0476 (4) | −0.0010 (3) | 0.0090 (3) | −0.0029 (3) |
N1 | 0.029 (2) | 0.0389 (18) | 0.045 (2) | −0.0045 (15) | −0.0011 (17) | 0.0001 (15) |
N2 | 0.0393 (18) | 0.0322 (17) | 0.043 (2) | −0.0033 (14) | 0.0031 (15) | −0.0074 (15) |
N3 | 0.058 (2) | 0.030 (2) | 0.055 (2) | −0.0104 (17) | 0.0117 (18) | −0.0024 (19) |
N4 | 0.0288 (18) | 0.0346 (17) | 0.046 (2) | −0.0015 (13) | 0.0043 (15) | 0.0027 (15) |
N5 | 0.053 (2) | 0.038 (2) | 0.053 (2) | 0.0070 (17) | 0.020 (2) | −0.0006 (18) |
N6 | 0.045 (2) | 0.0368 (19) | 0.048 (2) | −0.0028 (16) | 0.0147 (17) | −0.0011 (17) |
N7 | 0.0276 (18) | 0.0359 (16) | 0.048 (2) | 0.0037 (13) | 0.0118 (15) | −0.0020 (15) |
N8 | 0.031 (2) | 0.0453 (19) | 0.051 (2) | 0.0102 (16) | 0.0065 (18) | −0.0012 (16) |
N9 | 0.048 (2) | 0.063 (2) | 0.073 (3) | 0.0107 (18) | 0.025 (2) | −0.0060 (19) |
N10 | 0.071 (3) | 0.060 (3) | 0.059 (2) | 0.001 (2) | 0.029 (2) | −0.005 (2) |
O1 | 0.141 (3) | 0.074 (2) | 0.102 (3) | −0.048 (2) | −0.019 (2) | 0.032 (2) |
O2 | 0.099 (3) | 0.081 (3) | 0.188 (4) | −0.0103 (19) | −0.011 (3) | 0.035 (2) |
O3 | 0.258 (4) | 0.073 (2) | 0.132 (4) | 0.022 (3) | 0.045 (4) | 0.000 (2) |
Geometric parameters (Å, º) top
C1—N3 | 1.369 (4) | C23—C24 | 1.482 (4) |
C1—C2 | 1.384 (4) | C24—N6 | 1.467 (4) |
C1—C6 | 1.387 (4) | C24—H24A | 0.9700 |
C2—C3 | 1.374 (4) | C24—H24B | 0.9700 |
C2—H2 | 0.9300 | C25—N6 | 1.466 (4) |
C3—C4 | 1.399 (4) | C25—C26 | 1.499 (4) |
C3—H3 | 0.9300 | C25—H25A | 0.9700 |
C4—C5 | 1.362 (4) | C25—H25B | 0.9700 |
C4—H4 | 0.9300 | C26—N9 | 1.316 (4) |
C5—C6 | 1.386 (4) | C26—N10 | 1.336 (4) |
C5—H5 | 0.9300 | C27—C32 | 1.381 (4) |
C6—N2 | 1.388 (4) | C27—N9 | 1.385 (4) |
C7—N2 | 1.313 (3) | C27—C28 | 1.394 (5) |
C7—N3 | 1.359 (4) | C28—C29 | 1.380 (5) |
C7—C8 | 1.489 (4) | C28—H28 | 0.9300 |
C8—N1 | 1.469 (3) | C29—C30 | 1.377 (5) |
C8—H8A | 0.9700 | C29—H29 | 0.9300 |
C8—H8B | 0.9700 | C30—C31 | 1.364 (5) |
C9—N1 | 1.469 (4) | C30—H30 | 0.9300 |
C9—C10 | 1.492 (4) | C31—C32 | 1.379 (4) |
C9—H9A | 0.9700 | C31—H31 | 0.9300 |
C9—H9B | 0.9700 | C32—N10 | 1.379 (4) |
C10—N4 | 1.316 (4) | C33—O1 | 1.318 (4) |
C10—N5 | 1.346 (4) | C33—H33A | 0.9600 |
C11—N5 | 1.373 (4) | C33—H33B | 0.9600 |
C11—C16 | 1.376 (4) | C33—H33C | 0.9600 |
C11—C12 | 1.401 (4) | C34—O2 | 1.377 (4) |
C12—C13 | 1.371 (5) | C34—H34A | 0.9600 |
C12—H12 | 0.9300 | C34—H34B | 0.9600 |
C13—C14 | 1.387 (4) | C34—H34C | 0.9600 |
C13—H13 | 0.9300 | C35—O3 | 1.336 (4) |
C14—C15 | 1.389 (4) | C35—H35A | 0.9600 |
C14—H14 | 0.9300 | C35—H35B | 0.9600 |
C15—C16 | 1.392 (4) | C35—H35C | 0.9600 |
C15—H15 | 0.9300 | Mn—Cl2 | 2.425 (1) |
C16—N4 | 1.394 (3) | Mn—N1 | 2.444 (3) |
C17—C18 | 1.387 (4) | Mn—N2 | 2.187 (3) |
C17—C22 | 1.390 (4) | Mn—N4 | 2.202 (2) |
C17—N7 | 1.400 (4) | Mn—N6 | 2.389 (3) |
C18—C19 | 1.366 (4) | Mn—N7 | 2.204 (3) |
C18—H18 | 0.9300 | N1—H1N | 0.93 (2) |
C19—C20 | 1.386 (4) | N3—H3N | 0.888 (10) |
C19—H19 | 0.9300 | N5—H5N | 0.898 (10) |
C20—C21 | 1.381 (4) | N6—H6N | 0.92 (3) |
C20—H20 | 0.9300 | N8—H8N | 0.890 (10) |
C21—C22 | 1.386 (4) | N10—H10N | 0.899 (10) |
C21—H21 | 0.9300 | O1—H1 | 0.8200 |
C22—N8 | 1.379 (4) | O2—H2A | 0.8200 |
C23—N7 | 1.309 (3) | O3—H3A | 0.8200 |
C23—N8 | 1.341 (4) | | |
| | | |
N3—C1—C2 | 131.8 (4) | N10—C26—C25 | 122.5 (4) |
N3—C1—C6 | 105.9 (3) | C32—C27—N9 | 110.2 (4) |
C2—C1—C6 | 122.3 (4) | C32—C27—C28 | 119.7 (4) |
C3—C2—C1 | 117.2 (3) | N9—C27—C28 | 130.1 (5) |
C3—C2—H2 | 121.4 | C29—C28—C27 | 116.9 (5) |
C1—C2—H2 | 121.4 | C29—C28—H28 | 121.6 |
C2—C3—C4 | 120.8 (4) | C27—C28—H28 | 121.6 |
C2—C3—H3 | 119.6 | C30—C29—C28 | 122.3 (5) |
C4—C3—H3 | 119.6 | C30—C29—H29 | 118.9 |
C5—C4—C3 | 121.6 (4) | C28—C29—H29 | 118.9 |
C5—C4—H4 | 119.2 | C31—C30—C29 | 121.4 (5) |
C3—C4—H4 | 119.2 | C31—C30—H30 | 119.3 |
C4—C5—C6 | 118.4 (3) | C29—C30—H30 | 119.3 |
C4—C5—H5 | 120.8 | C30—C31—C32 | 116.8 (5) |
C6—C5—H5 | 120.8 | C30—C31—H31 | 121.6 |
C5—C6—C1 | 119.8 (4) | C32—C31—H31 | 121.6 |
C5—C6—N2 | 130.8 (3) | C31—C32—N10 | 132.2 (5) |
C1—C6—N2 | 109.4 (3) | C31—C32—C27 | 123.0 (4) |
N2—C7—N3 | 112.6 (3) | N10—C32—C27 | 104.8 (4) |
N2—C7—C8 | 124.2 (3) | O1—C33—H33A | 109.5 |
N3—C7—C8 | 123.0 (3) | O1—C33—H33B | 109.5 |
N1—C8—C7 | 110.8 (3) | H33A—C33—H33B | 109.5 |
N1—C8—H8A | 109.5 | O1—C33—H33C | 109.5 |
C7—C8—H8A | 109.5 | H33A—C33—H33C | 109.5 |
N1—C8—H8B | 109.5 | H33B—C33—H33C | 109.5 |
C7—C8—H8B | 109.5 | O2—C34—H34A | 109.5 |
H8A—C8—H8B | 108.1 | O2—C34—H34B | 109.5 |
N1—C9—C10 | 108.9 (3) | H34A—C34—H34B | 109.5 |
N1—C9—H9A | 109.9 | O2—C34—H34C | 109.5 |
C10—C9—H9A | 109.9 | H34A—C34—H34C | 109.5 |
N1—C9—H9B | 109.9 | H34B—C34—H34C | 109.5 |
C10—C9—H9B | 109.9 | O3—C35—H35A | 109.5 |
H9A—C9—H9B | 108.3 | O3—C35—H35B | 109.5 |
N4—C10—N5 | 113.2 (3) | H35A—C35—H35B | 109.5 |
N4—C10—C9 | 122.6 (3) | O3—C35—H35C | 109.5 |
N5—C10—C9 | 124.2 (3) | H35A—C35—H35C | 109.5 |
N5—C11—C16 | 106.1 (3) | H35B—C35—H35C | 109.5 |
N5—C11—C12 | 131.7 (4) | N2—Mn—N4 | 95.50 (9) |
C16—C11—C12 | 122.2 (4) | N2—Mn—N7 | 154.4 (1) |
C13—C12—C11 | 116.1 (4) | N4—Mn—N7 | 94.9 (1) |
C13—C12—H12 | 122.0 | N2—Mn—N6 | 88.7 (1) |
C11—C12—H12 | 122.0 | N4—Mn—N6 | 161.39 (11) |
C12—C13—C14 | 122.6 (4) | N7—Mn—N6 | 74.5 (1) |
C12—C13—H13 | 118.7 | N2—Mn—Cl2 | 101.73 (8) |
C14—C13—H13 | 118.7 | N4—Mn—Cl2 | 100.79 (8) |
C13—C14—C15 | 120.9 (4) | N7—Mn—Cl2 | 99.22 (7) |
C13—C14—H14 | 119.6 | N6—Mn—Cl2 | 96.06 (8) |
C15—C14—H14 | 119.6 | N2—Mn—N1 | 74.1 (1) |
C14—C15—C16 | 117.2 (3) | N4—Mn—N1 | 72.5 (1) |
C14—C15—H15 | 121.4 | N7—Mn—N1 | 86.9 (1) |
C16—C15—H15 | 121.4 | N6—Mn—N1 | 91.4 (1) |
C11—C16—C15 | 120.9 (4) | Cl2—Mn—N1 | 171.39 (8) |
C11—C16—N4 | 109.5 (3) | C9—N1—C8 | 113.7 (3) |
C15—C16—N4 | 129.5 (3) | C9—N1—Mn | 105.52 (18) |
C18—C17—C22 | 119.5 (3) | C8—N1—Mn | 110.2 (2) |
C18—C17—N7 | 131.1 (3) | C9—N1—H1N | 107.7 (17) |
C22—C17—N7 | 109.4 (3) | C8—N1—H1N | 108.3 (16) |
C19—C18—C17 | 117.6 (3) | Mn—N1—H1N | 111.5 (16) |
C19—C18—H18 | 121.2 | C7—N2—C6 | 105.2 (3) |
C17—C18—H18 | 121.2 | C7—N2—Mn | 117.6 (2) |
C18—C19—C20 | 122.7 (3) | C6—N2—Mn | 136.9 (2) |
C18—C19—H19 | 118.6 | C7—N3—C1 | 107.0 (3) |
C20—C19—H19 | 118.6 | C7—N3—H3N | 119 (2) |
C21—C20—C19 | 120.7 (3) | C1—N3—H3N | 134 (2) |
C21—C20—H20 | 119.6 | C10—N4—C16 | 104.5 (3) |
C19—C20—H20 | 119.6 | C10—N4—Mn | 116.1 (2) |
C20—C21—C22 | 116.3 (3) | C16—N4—Mn | 139.1 (2) |
C20—C21—H21 | 121.8 | C10—N5—C11 | 106.7 (3) |
C22—C21—H21 | 121.8 | C10—N5—H5N | 127 (2) |
N8—C22—C21 | 131.4 (3) | C11—N5—H5N | 126 (2) |
N8—C22—C17 | 105.5 (3) | C25—N6—C24 | 111.9 (3) |
C21—C22—C17 | 123.1 (3) | C25—N6—Mn | 113.5 (2) |
N7—C23—N8 | 113.9 (3) | C24—N6—Mn | 112.02 (19) |
N7—C23—C24 | 124.7 (3) | C25—N6—H6N | 106.5 (19) |
N8—C23—C24 | 121.4 (3) | C24—N6—H6N | 106 (2) |
N6—C24—C23 | 111.7 (3) | Mn—N6—H6N | 106.1 (17) |
N6—C24—H24A | 109.3 | C23—N7—C17 | 104.3 (3) |
C23—C24—H24A | 109.3 | C23—N7—Mn | 116.9 (2) |
N6—C24—H24B | 109.3 | C17—N7—Mn | 138.6 (2) |
C23—C24—H24B | 109.3 | C23—N8—C22 | 106.9 (3) |
H24A—C24—H24B | 107.9 | C23—N8—H8N | 126 (2) |
N6—C25—C26 | 116.1 (3) | C22—N8—H8N | 127 (2) |
N6—C25—H25A | 108.3 | C26—N9—C27 | 104.4 (3) |
C26—C25—H25A | 108.3 | C26—N10—C32 | 107.5 (4) |
N6—C25—H25B | 108.3 | C26—N10—H10N | 130.0 (19) |
C26—C25—H25B | 108.3 | C32—N10—H10N | 122.2 (19) |
H25A—C25—H25B | 107.4 | C33—O1—H1 | 109.5 |
N9—C26—N10 | 113.1 (3) | C34—O2—H2A | 109.5 |
N9—C26—C25 | 124.4 (4) | C35—O3—H3A | 109.5 |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
O1—H1···O2 | 0.82 | 1.82 | 2.627 (4) | 167 |
O2—H2A···N9 | 0.82 | 1.93 | 2.698 (4) | 155 |
O3—H3A···Cl1i | 0.82 | 2.34 | 3.114 (4) | 158 |
N1—H1N···Cl1i | 0.93 (2) | 2.54 (2) | 3.247 (3) | 133 (2) |
N3—H3N···O1ii | 0.89 (1) | 1.88 (1) | 2.724 (4) | 158 (3) |
N5—H5N···Cl2i | 0.90 (1) | 2.26 (1) | 3.155 (3) | 171 (3) |
N6—H6N···Cl1i | 0.92 (3) | 2.41 (3) | 3.292 (3) | 161 (3) |
N8—H8N···Cl1iii | 0.89 (1) | 2.21 (1) | 3.096 (3) | 178 (3) |
N10—H10N···O3 | 0.90 (1) | 1.91 (2) | 2.754 (4) | 156 (3) |
C4—H4···Cl2iv | 0.93 | 2.67 | 3.603 (4) | 174 |
Symmetry codes: (i) −x+1, y+1/2, −z+3/2; (ii) x, y+1, z; (iii) x+1, y, z; (iv) −x+1, −y+1, −z+1. |