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Acta Cryst. (2005). E61, m1652-m1654  [ doi:10.1107/S1600536805023536 ]

Bis{bis[2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-triene]potassium(I)} bis(2-thioxo-4,5-dihydro-1,3-dithiole-4,5-dithiolato)zinc(II)

J. Liu, J.-H. Zhang, D.-Q. Wang and J.-M. Dou

Abstract: The title complex, [K(C14H20O5)2]2[Zn(C3S5)2] or [K(B-15-C-5)2]2[Zn(dmit)2] (B-15-C-5 = benzo15-crown-5 and dmit = 4,5-dimercapto-1,3-dithiole-2-thione), contains two {[K(B-15-C-5)2]2}+ complex cations and one [Zn(dmit)2]2- complex anion in the asymmetric unit. The complex has a three-dimensional network structure assembled by intermolecular S...S and weak C-H...S interactions.

Online 30 July 2005


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