Acta Cryst. (2005). E61, m1495-m1497 [ doi:10.1107/S1600536805021276 ]
Abstract: The title compound, tetrasodium bis[tris(salicylatotitanate(IV)] undecahydrate, Na4[Ti(C7H4O3)3]2·11H2O, crystallizes with two titanium salicylate complex ions, four sodium ions and 11 water molecules in the asymmetric unit. One water O atom is disordered over two positions, having 0.74 (5) and 0.26 (5) occupancy. Both Ti atoms and three sodium ions adopt a distorted octahedral coordination by O atoms. The fourth sodium ion has a distorted trigonal-bipyramidal coordination by oxygen, sharing one edge with a sodium coordination octahedron.
Online 9 July 2005
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