Acta Cryst. (2005). E61, m1444-m1446  [ doi:10.1107/S1600536805020593 ]

The two-dimensional network polymer of (ethanol)(₃-N-salicyclideneglycinato)nickel(II)

Y.-Z. Yuan, J. Zhou, D.-Q. Li, X. Liu, Z.-F. Chen and K.-B. Yu

Abstract: In the title complex, [Ni(C₉H₇NO₃)(C₂H₆O)]_n, each Ni atom is octahedrally coordinated by four O atoms and one N atom from three fully deprotonated N-salicylideneglycinate (salgly) anions and by one O atom from an ethanol molecule. Two inversion-related Ni²⁺ ions are bridged by two O atoms from the phenolate groups of two salgly anions, forming a centrosymmetric dimeric unit which is further linked by carboxylate O atoms to give a two-dimensional network coordination polymer in the bc plane.

Online 6 July 2005

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