Acta Cryst. (2005). E61, m1447-m1448  [ doi:10.1107/S1600536805020313 ]

Hexacarbonylbis(₂-2-methoxyphenylthiolato)diiron(I)(Fe-Fe)

Y.-T. Si, C.-B. Ma, M.-Q. Hu and C.-N. Chen

Abstract: In the title compound, [Fe₂(CO)₆(C₇H₇OS)₂] or [Fe₂(SPh-2-OMe)₂(CO)₆], each Fe atom is coordinated by three terminal carbonyl C atoms [Fe-C 1.779  (2)-1.819  (2)  Å], two bridging S atoms [Fe-S 2.2747  (7)-2.2933  (7)  Å] and the other Fe atom [Fe-Fe 2.4979  (5)  Å], displaying a highly distorted octahedral geometry with cis angles ranging from 74.59  (3) to 105.88  (7)°.

Online 6 July 2005

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