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Acta Cryst. (2005). E61, m1447-m1448  [ doi:10.1107/S1600536805020313 ]

Hexacarbonylbis([mu]2-2-methoxyphenylthiolato)diiron(I)(Fe-Fe)

Y.-T. Si, C.-B. Ma, M.-Q. Hu and C.-N. Chen

Abstract: In the title compound, [Fe2(CO)6(C7H7OS)2] or [Fe2(SPh-2-OMe)2(CO)6], each Fe atom is coordinated by three terminal carbonyl C atoms [Fe-C 1.779 (2)-1.819 (2) Å], two bridging S atoms [Fe-S 2.2747 (7)-2.2933 (7) Å] and the other Fe atom [Fe-Fe 2.4979 (5) Å], displaying a highly distorted octahedral geometry with cis angles ranging from 74.59 (3) to 105.88 (7)°.

Online 6 July 2005


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