Acta Cryst. (2005). E61, m1492-m1494  [ doi:10.1107/S1600536805020520 ]

Dichlorobis[2-(3,5-dimethylpyrazolyl-1-carbonyl)furan]palladium(II) bis[aquatris(pentafluorophenyl)boron] dihydrate dichloromethane disolvate

I. A. Guzei, S. O. Ojwach and J. Darkwa

Abstract: Reaction of the Pd complex [(3,5-Me₂pz-CO-furan)₂PdCl₂] (where pzH is pyrazole) and the Lewis acid B(C₆F₅)₃ in the presence of adventitious water resulted in the formation of the title compound, [PdCl₂(C₁₀H₁₀N₂O₂)₂]·2C₁₈HBF₁₅O₂·2H₂O·2CH₂Cl₂, in 60% yield. The Pd complex occupies a crystallographic inversion center and exhibits a square-planar geometry. The two proposed dichloromethane molecules in the formula are highly disordered.

Online 9 July 2005

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