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Acta Cryst. (2005). E61, m1478-m1480  [ doi:10.1107/S1600536805020866 ]

catena-Poly[[bis(ethane-1,2-diaminium) [ferrate(III)-[mu]-hydroxo-[kappa]2O:O-di-[mu]-sulfato-[kappa]4O:O']] sulfate monohydrate]

Y.-L. Fu, Z.-W. Xu, J.-L. Ren and S. W. Ng

Abstract: The reaction of ferric sulfate with ethylenediamine in the presence of acid under hydrothermal conditions results in the title compound, (C2H10N2)2[FeIII(OH)(SO4)2](SO4)·H2O. The six-coordinate ferrate dianion participates in a [mu]2-hydroxo-di-[mu]2-sulfate-bridged chain. The component species interact with each other by an extensive network of O-H...O and N-H...O hydrogen bonds. The two independent FeIII atoms lie on sites of \\overline{1} symmetry.

Online 6 July 2005


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