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Acta Cryst. (2005). E61, m1517-m1519  [ doi:10.1107/S1600536805021197 ]

Tetra-[mu]-phenoxyacetato-bis[(acetonitrile)copper(II)](Cu-Cu)

G.-Q. Jiang, Y.-Z. Li, S.-N. Wang, F.-F. Li, Z.-J. Xu and J.-F. Bai

Abstract: The title centrosymmetric compound, [Cu2(C8H7O3)4(C2H3N)2], is a carboxylate-bridged dinuclear CuII complex with four phenoxyacetate and two acetonitrile molecules as ligands. Each of the four phenoxyacetate anions straddles the pair of Cu atoms, the Cu-Cu distance being 2.6618 (10) Å. A weak C-H...[pi] interaction connects the dinuclear CuII units into a one-dimensional chain.

Online 9 July 2005


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