Acta Cryst. (2005). E61, m1593-m1594 [ doi:10.1107/S1600536805022488 ]
Abstract: In the title compound, [Co(C15H18N5OS)2]BF4, the cation has a distorted octahedral geometry around the CoIII atom, with two 2,3-dimethyl-5-oxo-1-phenyl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethylthiosemicarbazonate anions coordinated as meridional tridentate ligands through the thiolate S, the antipyrine O and the imine N atoms. A tetrafluoroborate anion balances the charge of the CoIII complex.
Online 20 July 2005
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