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Acta Cryst. (2005). E61, m1641-m1643  [ doi:10.1107/S1600536805023408 ]

catena-Poly[piperazinium(2+) [ferrate(III)-[mu]-hydroxo-[kappa]2O:O-di-[mu]-sulfato-[kappa]4O:O'] dihydrate]

Y.-L. Fu, Z.-W. Xu, J.-L. Ren and S. W. Ng

Abstract: In the crystal structure of the polymeric title compound, {(C4H12N2)[Fe(OH)(SO4)2]·2H2O}n, the anion exists as a linear chain whose two independent FeIII atoms both occupy special positions of \\overline{1} site symmetry. The two independent cations, which also lie on inversion sites, interact with the polyanionic chain and with the uncoordinated water molecules to form a tight-held three-dimensional network.

Online 27 July 2005


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