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Acta Cryst. (2005). E61, m1671-m1673  [ doi:10.1107/S1600536805023986 ]

Poly[[bis[(dimethyl sulfoxide)zinc(II)]-di-[mu]4-benzene-1,4-dicarboxylato] dimethyl sulfoxide pentasolvate]

S.-Y. Yang, L.-S. Long, R.-B. Huang, L.-S. Zheng and S. W. Ng

Abstract: In the crystal structure of the title compound, [Zn2(C8H4O4)2(C2H6OS)2]·5C2H6OS, four independent carboxylate units of the 1,4-benzenedicarboxylate groups chelate to two Zn atoms to give rise to -O-C-O-Zn...Zn- rings, the four O atoms around each zinc atom forming a square, above which is a dimethyl sulfoxide (DMSO) molecule and below which is the other Zn atom. The bridging mode of the 1,4-benzenedicarboxylate groups, one of which lies on a general position and the other two on inversion centers, leads to a layer structure having DMSO molecules between the layers. The uncoordinated solvent molecules account for about 80% of the volume of the unit cell.

Online 30 July 2005


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