Acta Cryst. (2005). E61, m1644-m1645  [ doi:10.1107/S160053680502338X ]

Nonacarbonyl-₃-N,N-diethyldithiocarbamato-³S:S:S'--hydrido-triosmium(3 Os-Os)

I. Garcia-Orozco, C. J. Pastor, B. Souto, E. Delgado, E. Hernández and C. Alvarez-Toledano

Abstract: The molecular structure of the title compound, [Os₃(C₅H₁₀NS₂)H(CO)₉], consists of an Os₃ triangle with a bridging dithiocarbamate ligand acting as a five-electron donor; a hydride ligand is located between two Os atoms. Three terminal carbonyl groups on each Os atom complete the structure. There are two independent molecules in the asymmetric unit.

Online 27 July 2005

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