Acta Cryst. (2005). E61, m1433-m1435 [ doi:10.1107/S1600536805020209 ]
Abstract: In the title compound, [Pt(C5H5NS)4]Cl2, the PtII ion is located at a crystallographic inversion centre, with each S-donor ligand in its thione tautomeric form [Pt-S = 2.3439 (7) and 2.3444 (7) Å]. The Cl- ion positioned at each axial site of the PtII ion [PtCl = 3.5171 (8) Å] is hydrogen-bonded to the N-H units of the ligands [ClN = 3.103 (3) and 3.125 (3) Å].
Online 6 July 2005
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