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Acta Cryst. (2005). E61, m1556-m1558  [ doi:10.1107/S1600536805021550 ]

catena-Poly[[[tripyridinecopper(II)]-[mu]-m-phenylenedioxydiacetato] monohydrate]

X.-L. Hong, Y.-Z. Li, G.-Q. Jiang and J.-F. Bai

Abstract: In the title compound, [Cu(C10H8O6)(C5H5N)3]·H2O, the coordination geometry around the CuII atom is distorted square-pyramidal, and the Cu-N bond at the apical position lies on a twofold axis. The m-phenylenedioxydiacetate ligand also has twofold symetry and acts as bridge to link Cu atoms to form infinite chains along the c axis. The solvent water molecule connects two adjacent carboxylate groups of the m-phenylenedioxydiacetates on the same chain via hydrogen bonds.

Online 13 July 2005


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