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Acta Cryst. (2005). E61, m1534-m1536  [ doi:10.1107/S1600536805021641 ]

Diaqua-[kappa]2O-tris(1,10-phenanthroline)-1[kappa]2N,N';2[kappa]4N,N'-[mu]-5-sulfonatoisophthalato-1:2[kappa]4O1,O1':O3,O3'-dicopper(II) perchlorate trihydrate

W.-D. Wang and X.-H. Li

Abstract: In the title compound, [Cu2(C8H3O7S)(C12H8N2)3(H2O)2]ClO4·3H2O, the 5-sulfonatoisophthalate trianion functions as a bridge between two Cu atoms to form an asymmetric dinuclear cation. One Cu atom is surrounded by four O atoms, two from a 5-sulfonatoisophthalate trianion and two from water ligands, and by two N atoms from a 1,10-phenanthroline ligand. The second Cu atom is bound to two O atoms from a 5-sulfonatoisophthalate trianion and four N atoms from two 1,10-phenanthroline ligands. Both copper centers have a distorted octahedral geometry.

Online 13 July 2005

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