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Acta Cryst. (2005). E61, m1635-m1636  [ doi:10.1107/S160053680502341X ]

Bis[(diphenylphosphino)acetato-[kappa]2O,P]palladium(II) dichloromethane solvate

M.-P. Guo, F.-F. Jian, R. He and H.-L. Xiao

Abstract: The title compound, [Pd(C14H12O2P)2]·CH2Cl2, consists of mononuclear [(Ph2PCH2COO)2Pd] complexes and dichloromethane molecules in a 1:1 molar ratio. The two (diphenylphosphino)acetate ligands are coordinated to the central Pd atom by their P and O atoms, forming five-membered chelate rings. The PdII atom has a distorted square-planar configuration [Pd-O = 2.076 (3) and 2.082 (3) Å, and Pd-P = 2.214 (1) and 2.216 (1) Å].

Online 27 July 2005


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