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Acta Cryst. (2005). E61, m1588-m1589  [ doi:10.1107/S1600536805020052 ]

(Acetonitrile-[kappa]N){1,2-bis[bis(pentafluorophenyl)phosphino]ethane-[kappa]2P,P}([eta]5-pentamethylcyclopentadienyl)ruthenium(II) hexafluorophosphate

R. M. Bellabarba, M. Nieuwenhuyzen and G. C. Saunders

Abstract: The cation of the title salt, [Ru([eta]5-C5Me5)(NCMe){(C6F5)2PCH2CH2P(C6F5)2}]PF6 or [Ru(C10H15)(C26H4F20P2)(C2H3N)]PF6, has contacts with three anions. One lies close to the pentamethylcyclopentadienyl ring, such that three F atoms of the anion are ca 3.5 Å from two of the ring methyl C atoms of the cation and there is one H...F distance shorter than the sum of the van der Waals radii.

Online 16 July 2005


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