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Acta Cryst. (2005). E61, m1548-m1549  [ doi:10.1107/S1600536805021677 ]

Bis([mu]-2,4-dihydroxyacetophenone salicylhydrazidato)bis[pyridinezinc(II)] dimethylformamide disolvate

J. Huang, Y. Wu and X. Zhu

Abstract: The tridentate Schiff base ligand 2,4-dihydroxyacetophenone salicylhydrazide, derived from the condensation of 2,4-dihydroxyacetophenone and salicylhydrazide, in the presence of pyridine and N,N'-dimethylformamide, forms a dinuclear distorted square-pyramidal Zn complex with Zn(OAc)2·2H2O, viz. [Zn2(C15H12N2O4)2(C5H5N)2]·2C3H7NO. The complex is centrosymmetric and the two Zn atoms are bridged by two phenolate O atoms.

Online 13 July 2005


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