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Acta Cryst. (2005). E61, m1475-m1477  [ doi:10.1107/S1600536805020982 ]

Di-[mu]-diphenylphosphido-bis[tricarbonyliron(II)] dichloromethane solvate

M. G. Ballinas-López, I. I. Padilla-Martínez, F. J. Martínez-Martínez, H. Höpfl and E. V. García-Báez

Abstract: In the crystal structure of the title compound, [Fe2(C12H10P)2(CO)6]·CH2Cl2, the complex molecule lies across a mirror plane. Two diphosphide ligands bridge two (CO)3Fe fragments to form a dinuclear complex, in which the Fe-Fe distance is 2.6701 (6) Å. Two aromatic rings within the same molecule interact by face-to-face [pi]-[pi] stacking, with a centroid-to-centroid distance of 3.601 (2) Å.

Online 6 July 2005


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