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Acta Cryst. (2005). E61, m1735-m1737  [ doi:10.1107/S1600536805024086 ]

Tris(1H-benzimidazole-[kappa]N3)(thiodiacetato-[kappa]3O,S,O')cadmium(II) dihydrate

T.-T. Pan and D.-J. Xu

Abstract: In the title complex, [Cd(C4H4O4S)(C7H6N2)3]·2H2O, the CdII atom is surrounded by three benzimidazole ligands and one thiodiacetate dianion to complete a distorted octahedral CdN3O2S coordination geometry. The tridentate TDA chelates to the CdII atom in a facial mode. A C-H...[pi] interaction and hydrogen bonding between neighboring complexes help to stabilize the crystal structure.

Online 12 August 2005


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